Structural overview of technetium compounds (2000–2004)

This paper provides an overview of the about 80 crystal structures of technetium complexes described in the past 5 years and exhibiting some peculiar structural features. In almost 90% of the compounds, technetium shows an odd oxidation number, and by a large majority the revised complexes are monon...

Full description

Saved in:
Bibliographic Details
Published in:Coordination chemistry reviews 2006-02, Vol.250 (3), p.561-573
Main Authors: Bandoli, Giuliano, Tisato, Francesco, Dolmella, Alessandro, Agostini, Stefania
Format: Article
Language:English
Subjects:
[Tc(CO) 3] + complexes
Nitrido-Tc(V) complexes
Oxo-Tc(V) complexes
Tc(III) complexes
X-ray structures
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:This paper provides an overview of the about 80 crystal structures of technetium complexes described in the past 5 years and exhibiting some peculiar structural features. In almost 90% of the compounds, technetium shows an odd oxidation number, and by a large majority the revised complexes are mononuclear and neutral. The review especially focuses on nitrido-Tc(V), oxo-Tc(V) and fac-[Tc(CO) 3] + complexes, which cover approximately one-half of the X-ray structural reports.
ISSN:0010-8545
1873-3840
DOI:10.1016/j.ccr.2005.09.012