Lewis acid catalysis on single site Sn centers incorporated into silica hosts

• Published in: Coordination chemistry reviews 2017-07, Vol.343, p.220-255
• Main Authors: Ferrini, Paola, Dijkmans, Jan, De Clercq, Rik, Van de Vyver, Stijn, Dusselier, Michiel, Jacobs, Pierre A., Sels, Bert F.
• Format: Article
• Language: English
• Subjects: Biomass; Lewis acid; Snβ; Stannosilicates; Zeolite
• ISSN: 0010-8545; 1873-3840
• DOI: 10.1016/j.ccr.2017.05.010

[Display omitted] •Synthesis, characterization and catalytic performance of Sn-silicates are reviewed.•Top-down approaches are safer and faster alternatives to hydrothermal synthesis.•Advanced analytical techniques are needed to answer open debates on Sn coordination.•Novel catalytic applications open new opportunities to employ stannosilicates.•Progresses in stability studies are essential for stannosilicates application. Tetrahedral Sn built into microporous silica frameworks such as zeolites and structured mesoporous silica can be used as heterogeneous Lewis acid catalysts. These materials have recently attracted much attention, as they show remarkable activity and selectivity in a wide range of reactions. A prominent example is the conversion of carbohydrates into platform and commodity chemicals such as lactic acid or alkyl lactates, where the activity and selectivity of Sn-based materials remains unsurpassed compared to Sn-free catalysts. Some of the materials show water-tolerant behavior and can therefore also be used in aqueous systems. In this work, a literature overview regarding synthesis of Sn-containing silica materials is given, as well as a synopsis of the characterization tools which can be used to unravel the structure of the catalytic active site. The application of such Sn-containing materials for diverse catalytic reactions is reviewed, with special emphasis on the effects of the catalyst characteristics on the catalytic activity and stability.