Multivariate crystalline porous materials: Synthesis, property and potential application

[Display omitted] •The synthesis, property and potential application of multivariate crystalline porous materials are overviewed.•Multivariate strategy improves structural stability, gas uptake capacity, sensing selectivity and catalytic activity of CPMs.•MTV-CPMs provide a powerful route to design...

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Bibliographic Details
Published in:Coordination chemistry reviews 2019-04, Vol.385, p.174-190
Main Authors: Jiao, Jingjing, Gong, Wei, Wu, Xiaowei, Yang, Shiping, Cui, Yong
Format: Article
Language:English
Subjects:
Covalent-organic frameworks
Metal-organic frameworks
Multivariate
Potential application
Property
Synthesis
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Summary:[Display omitted] •The synthesis, property and potential application of multivariate crystalline porous materials are overviewed.•Multivariate strategy improves structural stability, gas uptake capacity, sensing selectivity and catalytic activity of CPMs.•MTV-CPMs provide a powerful route to design desired functional porous materials. Crystalline porous materials (CPMs) including metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) have captured widespread interest in various fields, such as gas storage and separation, sensor, catalysis, energy storage, biological engineering, etc. With increasing demand for synthesis of more diverse and functionalized CPMs, multivariate synthetic strategy has been used extensively to design and prepare novel CPMs by taking advantage of tunable void space, specific functionalities and desired structural stability. In this review, we summary the recent research progress in synthesis, property and potential application of multivariate CPMs focusing on MOFs and COFs materials.
ISSN:0010-8545
1873-3840
DOI:10.1016/j.ccr.2019.01.016