Conductive properties of triphenylene MOFs and COFs

• Published in: Coordination chemistry reviews 2022-06, Vol.460, p.214459, Article 214459
• Main Authors: Contreras-Pereda, Noemí, Pané, Salvador, Puigmartí-Luis, Josep, Ruiz-Molina, Daniel
• Format: Article
• Language: English
• Subjects: COF; Electronic; Functional device; MOF; Triphenylene; Two-dimensional
• ISSN: 0010-8545; 1873-3840
• DOI: 10.1016/j.ccr.2022.214459

•Use of active metal ions/triphenylene ligands for the fabrication of MOFs and COFs.•Conductive properties.•2D materials.•Synthesis approaches towards control grain boundaries and crystal anisotropy.•Emerging devices. Triphenylene (TP) based materials have experienced a great expansion in the latest years. TP molecules have interesting optoelectronic properties, arising from the aromatic core, which have been exploited in functional two-dimensional (2D) Metal-Organic Frameworks (MOFs) and Covalent Organic Frameworks (COFs) aside other organic polymers. In this review we summarize synthetic approaches of TP-based 2D MOFs and COFs emphasizing on the resulting morphology, crystalline domains and orientation, proven to have great impact on the properties and performance of these materials in functional devices. Specifically, we report a detailed description on the different TP-based 2D structures detailing the influence of the chemical and crystalline structure on the electronic properties, specially the in-plane and out-of-plane contribution to the electrical conductivity. Finally, we give also attention and present several examples of functional devices made out with these electronic materials with great impact in the literature as well as in future technological applications.