Adsorption of furfural from torrefaction condensate using torrefied biomass

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2018-02, Vol.334, p.558-568
• Main Authors: Doddapaneni, Tharaka Rama Krishna C., Jain, Rohan, Praveenkumar, Ramasamy, Rintala, Jukka, Romar, Henrik, Konttinen, Jukka
• Format: Article
• Language: English
• Subjects: Anaerobic digestion; Detoxification; Energy densification; Pellets; Torrefaction volatiles
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2017.10.053

[Display omitted] •Adsorption of furfural onto torrefied biomass was reported for the first time.•Methane production significantly improved with proposed detoxification approach.•An integrated torrefaction process to produce pellets and methane was proposed. Torrefaction is a biomass energy densification process that generates a major byproduct in the form of torrefaction condensate. Microbial conversion of torrefaction condensate could be an attractive option for energy integration within torrefaction process. However, torrefaction condensate contains several compounds, such as furfural, 5-hydroxymethylfurfural and guaiacol that are inhibitory to microbes. In this study, for the first time, we reported detoxification of torrefaction condensate, by removing the major inhibitory compound furfural, using torrefied biomass and later used the detoxified torrefaction condensate for anaerobic digestion. The effect of varying torrefaction temperature (225–300°C), torrefied biomass dosage (25–250g/L), initial pH (2.0–9.0), and contact time (1–12h) on furfural adsorption was studied with batch adsorption experiments. The furfural adsorption on torrefied biomass was best represented by pseudo second order kinetic model. The adsorption of furfural and other inhibitory compounds on torrefied biomass was likely a hydrophobic interaction. A maximum of 60% of furfural was adsorbed from torrefaction condensate containing 9000mgfurfural/L using 250g/L of torrefied biomass in batch adsorption. For, column (20mm internal diameter and 200mm bed height), the saturation time for furfural adsorption was around 50min. Anaerobic digestion of the detoxified torrefaction condensate shows that the lag phase in methane production was reduced from 25d to 15d for 0.2 volatile solid (VS)substrate:VSinoculum loading. The study shows that torrefaction condensate can be effectively detoxified using torrefied biomass for microbial conversion and can be integrated within the torrefied biomass pellet production process.