Enhanced thermoelectric properties of YbZn2Sb2−xBix through a synergistic effect via Bi-doping

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2019-10, Vol.374, p.589-595
• Main Authors: Zhang, Xiong, Gu, Haoshuang, Zhang, Yu, Guo, Lijie, Yang, Juntao, Luo, Shijun, Lu, Xu, Chen, Kansong, Chai, Hongxiang, Wang, Guoyu, Zhang, Xiao, Zhou, Xiaoyuan
• Format: Article
• Language: English
• Subjects: Callaway model; Effective mass; Fermi level; Thermoelectric; Zintl compounds
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2019.05.206

•The effective mass is increased firstly by shifting the Fermi level.•The PF is enhanced by increased σ and maintained α.•The PF and κ are simultaneously improved by a synergistic effect via Bi doping.•Bi substitution on Sb-site is different from conventional substitution on cations. Recently, extensive research has been done to explore the potential thermoelectric performance of p-Type Zintl compounds AB2Sb2 (A = Ca, Yb, Eu, Sr, Mg; B = Zn, Mn, Cd, Mg), mainly focus on A-site substitution and/or B-site substitution effect. Herein, we report that both power factors and thermal conductivities are simultaneously optimized to increase ZT values via substitution of Sb atoms with the isoelectronic Bi atoms in YbZn2Sb2−xBix compounds. We found that the power factor could be enhanced by 27%, as a result of improved electrical conductivities and the maintained Seebeck coefficients. The former is obtained from an increase of carrier density through a shift of Fermi level via Bi doping, which is supported by XPS analysis. The Seebeck coefficients are maintained due to the increased effective mass. Moreover, the lowest lattice thermal conductivity (0.47 Wm−1 K−1 at 723K) is below the lattice thermal conductivity limit due to enhanced phonon scattering via Bi-doping, which is analyzed by the Callaway model. Benefiting from the synergistic effect, the ZT of Bi-doping samples are significantly enhanced compared with that of the pristine one. These results probably offer a synergistic strategy to enhance ZT for p-Type Zintl compounds AB2Sb2 and other high-efficiency thermoelectric materials.