Z-scheme AgVO3/ZnIn2S4 photocatalysts: “One Stone and Two Birds” strategy to solve photocorrosion and improve the photocatalytic activity and stability

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2020-10, Vol.398, p.125523, Article 125523
• Main Authors: Li, Chunxue, Che, Huinan, Yan, Yongsheng, Liu, Chunbo, Dong, Hongjun
• Format: Article
• Language: English
• Subjects: AgVO3; Photocatalysis; Z-scheme heterojunction; ZnIn2S4
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2020.125523

[Display omitted] •A photocatalyst solved two urgent problems simultaneously, that is, it has the property of “One Stone and Two Birds”.•Effects of various parameters on Cr (VI) reduction were studied systematically.•Toxicity assessment after photocatalytic reaction were studied.•The 20% AgVO3/ZnIn2S4 exhibited the top-flight photoreduction Cr (VI) activity.•AgVO3/ZnIn2S4 were universal for photodegradation of Cr (VI) and antibiotics. At present, photocorrosion is one of the factors that seriously restrict the improvement of photocatalytic performance. Herein, we successfully constructed AgVO3/ZnIn2S4 composite photocatalysts with the property of “One Stone and Two Birds”, which solved two urgent problems simultaneously, the S-metal bonds of sulfide are easily oxidized by photogenerated holes and the Ag+ of Ag-based photocatalysts are easily reduced by photogenerated electrons. Additionally, the Ag NPs were precipitated automatically during the synthesis of AgVO3/ZnIn2S4, which favor to enhance the transfer rate of the photogenerated carriers and remain strong redox ability of the AgVO3/ZnIn2S4 photocatalysts. The as-prepared 20% AgVO3/ZnIn2S4 exhibited the top-flight photocatalytic reduction of Cr (VI) activity. In addition, the effects of pH value and temperature on the photocatalytic reduction of Cr (VI) were investigated in depth. Simultaneously, the photocatalytic reduction activity was further verified based on biotoxicity assessments and toxicity predictions of the products. At the same time, the photocatalyst showed good photocatalytic degradation activity to 2-mercaptobenzothiazole (MBT) and ciprofloxacin (CIP). In addition, the AgVO3/ZnIn2S4 photocatalysts possessed superior cycle performance and structural stability. The enhanced activity and stability were ascribed to the successfully suppressed the photocorrosion of both AgVO3 and ZnIn2S4 by transferring the photogenerated electrons and holes to Ag NPs.