Mechanically robust and multifunctional polyimide/MXene composite aerogel for smart fire protection

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2022-04, Vol.434, p.134630, Article 134630
• Main Authors: Jiang, Changcheng, Chen, Jiayun, Lai, Xuejun, Li, Hongqiang, Zeng, Xingrong, Zhao, Yinan, Zeng, Qingtao, Gao, Jiefeng, Wu, Zhengzhong, Qiu, Yunkun
• Format: Article
• Language: English
• Subjects: Fire-warning; MXene; Piezoresistive sensing; Polyimide aerogel; Temperature sensing
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2022.134630

[Display omitted] •A multifunctional smart fireproof aerogel was fabricated with polyimide and MXene.•The aerogel could trigger the fire-alarm system within 5 s when being burned.•The aerogel exhibited high fire safety and self-extinguished within 1 s.•The aerogel could monitor temperature change in real time.•The aerogel showed excellent mechanical and piezoresistive sensing performance. Multifunctional smart fire-protection aerogels are urgently needed to meet the requirement of the Internet of Everything era. Herein, we fabricated a mechanically robust and high fire-safe polyimide/MXene composite aerogel (denoted as PI@MXene) with sensitive temperature-sensing and fire-warning capability. Thanks to the unique thermoelectric effect and high electrical conductivity of the 2D transition metal carbide (MXene) nanosheet, PI@MXene exhibited a linear relationship between the thermoelectric voltage and the temperature difference, showing sensitive temperature-sensing capability. When being burned, it could repeatedly trigger the fire-warning system in less than 5 s. More importantly, owing to the lamellar barrier and skeleton supporting effect of the MXene nanosheets, PI@MXene exhibited excellent flame retardancy, which self-extinguished within 1 s after exposing to a flame for 60 s and whose peak heat release rate was significantly decreased by 78% compared with PI aerogel. Besides, PI@MXene showed impressive thermal insulation, outstanding thermostability and durable piezoresistive sensing. This work provides a novel strategy to fabricate next-generation multifunctional fireproof aerogel, showing promising applications in intelligent robots, aerospace, and railway transportation.