Transparent polyurethane coating with synergistically enhanced antibacterial mechanism composed of low surface free energy and biocide

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2022-10, Vol.445, p.136716, Article 136716
• Main Authors: Ji, Jiujiang, Liu, Na, Tian, Ye, Li, Xiangyu, Zhai, Huajun, Zhao, Shuaiheng, Liu, Yue, Liu, Guojun, Wei, Yen, Feng, Lin
• Format: Article
• Language: English
• Subjects: Antibacterial; Polyurethane coating; Quaternary ammonium salts modified polysiloxanes; Self-renewability; Transparent
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2022.136716

[Display omitted] •Synergistically enhanced antibiosis composed of low surface energy and biocide.•The coating with the thickness of 15 μm displays 96 % light transmittance.•Clear coating shows antibacterial effect against E. coli (99%) and S. aureus (99%).•Coating behaves great self-renewability due to uniform distribution of nanopools. Recently, antibacterial coatings have gained great attention after the outbreak of COVID-19, thus durable transparent polyurethane (PU) coatings with anti-bacterial and anti-fingerprint performances are highly desired. In this work, the low surface free energy enables the hydroxyl-terminated polysiloxanes modified with quaternary ammonium salts (PQMS) enriched on the surface. The optimal PU-PQMS-40 % coating with the thickness of 15 μm displayed 96 % light transmittance and can be adopted to diverse substrates. This resultant coating exhibits excellent antibacterial activity against Gram-negative E. coli (99.2 %) and Gram-positive S. aureus (98.6 %) because of the synergistically enhanced antibacterial mechanism of both low surface free energy (27.54 ± 0.75 mJ·m−2) and quaternary ammonium salts (QAs). It is noteworthy that this antibacterial PU coating is capable of retaining its properties even after being subjected to 210 cycles of abrasion tests, manifesting a superior self-renewability. This coating system with combined features of transparency, antibacterial performance, chemical resistance, and durability make it a promising candidate for applications in the fields of electronic devices, automobile interiors, intelligent glass, and marine antifouling.