Intensified synthesis for ethyl lactate production including economic, sustainability and inherent safety criteria

• Published in: Chemical engineering and processing 2020-08, Vol.154, p.108041, Article 108041
• Main Authors: Tusso-Pinzón, Ricardo A., Castillo-Landero, Arick, Matallana-Pérez, Luis G., Jiménez-Gutiérrez, Arturo
• Format: Article
• Language: English
• Subjects: Dividing wall column; Ethyl lactate; Extractive distillation; Inherent safety; Process intensification; Simultaneous phenomena building blocks
• ISSN: 0255-2701; 1873-3204
• DOI: 10.1016/j.cep.2020.108041

[Display omitted] •A methodology for process intensification is presented.•The methodology takes a base flowsheet to gradually intensify the process.•The target is to generate a structure with a minimum number of equipment units.•Application to a process for the production of ethyl lactate is presented.•The intensified process provides improvements in major performance metrics. A methodology for gradual process intensification is applied to a conventional flowsheet for the production of the green solvent ethyl lactate from ethyl alcohol and lactic acid. The approach takes the base design and integrates two pieces of equipment into one at each step of the intensification task. The concepts of phenomena building blocks and simultaneous phenomena building blocks are used to track the intensification steps, and each intensified structure is rated through economic, environmental, sustainability and inherent safety metrics. The process involves the separation of an ethanol-water azeotropic mixture, for which an extractive distillation system is used. Two entrainers were considered for the extractive distillation process, one based on a mixture of ethylene glycol/glycerol, and the other one on acetol. The results of intensifying an original flowsheet with a reaction unit and 4 separating units into two pieces of equipment showed that significant economic savings and improvements in the sustainability and inherent metrics can be obtained.