New LiNi0.5PrxFe2−xO4 nanocrystallites: Synthesis via low cost route for fabrication of smart advanced technological devices

• Published in: Ceramics international 2017-12, Vol.43 (17), p.14807-14812
• Main Authors: Warsi, Mohamed Farooq, Gilani, Zaheer Abbas, Al-Khalli, Najeeb Fuad, Sarfraz, Mansoor, Khan, Muhammad Azhar, Anjum, Muhammad Naeem, Shakir, Imran
• Format: Article
• Language: English
• Subjects: Li-Pr; Magnetic properties; Nanocrystalline ferrites; Praseodymium; SEM
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2017.07.228

Praseodymium substituted nano-crystalline Li-Ni spinel ferrites with different Pr3+ contents were synthesized by micro-emulsion method. X-ray diffraction (XRD), scanning electron spectroscopy (SEM) and vibrating sample magnetometery (VSM) techniques were employed to study the impact of substitution of the Pr3+ on the structure, surface morphology and magnetic parameters. XRD confirmed the formation of the single phase spinel ferrites of all compositions of LiNi0.5PrxFe2−xO4 nanocrystallites. The crystallite size determined from XRD data by Scherrer formula was calculated in range from 40nm to 70nm. However the nanoparticles size estimated by SEM was found 35–115nm. The room temperature VSM measurements were carried out in the applied field range from “−10,000Oe” to “10000”Oe. Saturation magnetization (MS) (41emu/g) and coercivity (HC) values (156.9Oe) of LiNi0.5Fe2O4 were improved by the addition of rare earth Pr3+ cations. The value of Hc is low, which is a strong indication of soft ferrites. The synthesized LiNi0.5PrxFe2−xO4 ferrites may be utilized for low core losses on transformers.