Novel orange-emitting Ba2LaNbO6:Eu3+ nanophosphors for NUV-based WLEDs and photocatalytic water purification

• Published in: Ceramics international 2019-03, Vol.45 (4), p.4781-4789
• Main Authors: Pavitra, E., Raju, G. Seeta Rama, Ghoreishian, Seyed Majid, Kwak, Cheol Hwan, Park, Jin Young, Han, Young-Kyu, Huh, Yun Suk
• Format: Article
• Language: English
• Subjects: Nanophosphors; Photocatalysis; Photoluminescence; Sol-gel process
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2018.11.171

Energy conservation and environmental safety are the key requirements in the modern world. We report novel orange-emitting double perovskite Ba2LaNbO6:Eu3+ (BLN:Eu3+) nanophosphor fabricated using a citrate sol-gel method for use in general illumination and photocatalysis. After annealing at 800 ℃, the particles exhibited a nanorod-like morphology with monoclinic structure. The photoluminescence emission spectra exhibited an intense 5D0→7F1 transition at 594 nm and a moderate 5D0→7F2 transition at 615 nm, demonstrating that the Eu3+ ions occupied the La3+ sites with inversion symmetry. The optimal concentration of Eu3+ ions was found to be about 5 mol% for the BLN host lattice. Energy transfer from the NbO67- octahedrons to the Eu3+ ions was clearly witnessed when the BLN:Eu3+ nanophosphors were excited with both the characteristic excitation bands of Eu3+ (7F0→5L6) and NbO67- octahedrons at 392 and 380 nm, respectively. The thermal quenching temperature of 5 mol% Eu3+ ions doped BLN nanophosphors was found to be 183 ℃, indicating that these nanophosphors are very stable at high temperatures. In addition, the dye removal efficiency of the proposed BLN nanophosphors was verified using Rhodamine B (RhB) dye as a model pollutant under UV irradiation. Compared to a commercial nano-ZnO catalyst, our synthesized BLN nanophosphors showed superior RhB de-colorization efficiency. Therefore, the proposed BLN:Eu3+ nanophosphors are promising multifunctional materials for photocatalysis and general lighting applications.