Effect of Y doping on transport properties of La0.8Sr0.2MnO3 polycrystalline ceramics

• Published in: Ceramics international 2020-06, Vol.46 (8), p.11950-11954
• Main Authors: Wang, Chengyi, Zhang, Hui, Li, Yule, Yang, Sheng'an, Chen, Qingming
• Format: Article
• Language: English
• Subjects: La0.8-xYxSr0.2MnO3 (LYSMO); Magnetoresistance (MR); Resistivity (ρ); Sol–gel method; Temperature coefficient of resistance (TCR)
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2020.01.233

In this study, La0.8-xYxSr0.2MnO3 (LYSMO) polycrystalline ceramics were prepared by means of sol-gel technique using methanol as solvent. X-ray diffraction (XRD) showed all samples to possess standard perovskite structure. Scanning electron microscopy (SEM) revealed samples with high compactness and grain size from 27.80 to 29.73 μm. Resistivity–temperature tests indicated sharp metal-insulator transition behavior of all samples accompanied by rapid transformation from ferromagnetism to paramagnetism (FM-PM). As Y3+ doping amounts rose, radius of A-site ions decreased, metal-insulator transition temperature (Tp) of polycrystalline samples shifted to lower temperatures, and resistivity increased. Temperature coefficient of resistance (TCR) and magnetoresistance (MR) were affected by introduction of Y3+. At x = 0.06, peak TCR and peak MR reached 4.85% K−1 and 52.34%, respectively. Using double exchange (DE) interaction mechanism, electric transport performances of as-prepared ceramics were explained. These findings look promising for future applications of LYSMO materials in magnetic devices and infrared detectors.