Preparation and mechanical properties of laminated B4C–TiB2/BN ceramics

• Published in: Ceramics international 2021-11, Vol.47 (22), p.31214-31221
• Main Authors: Wang, Bo, Cai, Delong, Xue, Chengyong, Niu, Bo, Yang, Zhihua, Duan, Xiaoming, Li, Daxin, Jia, Dechang, Zhou, Yu
• Format: Article
• Language: English
• Subjects: Crack deflection; Fracture toughness; Laminated B4C–TiB2/BN ceramics; Mechanical properties
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2021.07.297

Laminated B4C–TiB2 ceramics with h-BN interface layers were successfully prepared by roll forming and tape casting, and samples with different numbers of stacked layers were obtained. Scanning electron microscopy and X-ray diffraction were used to analyze the microstructure and interlayer crystal phases of the composites, and the bending strength, fracture toughness, and work of fracture were measured. As the number of h-BN layers increased, the fracture toughness increased from 7.38 ± 0.5 MPa m1/2 to 9.01 ± 0.61 MPa m1/2, which is 2–3 times higher than that of monolithic B4C ceramics. As the fracture toughness increased, the hardness remained at a high level (31.67 GPa). Bending tests showed that cracks deflected when they encountered the h-BN interfacial layers. The toughening mechanisms included the deflection and branching of cracks and generation of new microcracks, which increased the length of the propagation path and work of fracture.