Natural fuel assisted synthesis of Mg–Cu ferrite nanoparticles: Evaluation of structural, dielectric, magnetic and humidity sensing properties

• Published in: Ceramics international 2022-02, Vol.48 (4), p.4874-4885
• Main Authors: Balamurugan, A., Priya, R. Shunmuga, Chaudhary, Priyanka, Kumar, E. Ranjith, Indumathi, T., Srinivas, Ch, Yadav, B.C., Sastry, D.L.
• Format: Article
• Language: English
• Subjects: Dielectric properties; Green synthesis; Humidity sensor; Structural analysis; TEM
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2021.11.024

The effects of lemon juice and annealing treatment on phase composition, vibrational modes, microstructural and dielectric behavior of Mg doped copper ferrite nanoparticles have been synthesized and analyzed in detail in this present work. The various characterization techniques are used to examine the phase, microstructural, vibrational and dielectric nature of the samples at different annealing temperatures (600 °C and 900 °C). The phase and microstructure of Mg substituted CuFe2O4 nanoparticles have been analyzed by XRD, SEM and TEM. The secondary phase peaks free XRD spectra revealed that the as burst and the annealed Mg–CuFe2O4 nanoparticles have single phase cubic spinel structure. The average crystallite size of the as burnt, annealed 600 °C and annealed 900 °C of as prepared nanoparticles are calculated as 8.9 nm, 12.8 nm and 31.6 nm respectively. Another verification of the spherical shaped particle's size was confirmed by TEM analysis and it found as average size of 28.7 nm, this result is well matched with XRD analysis. The effect of size with impact of annealing treatment on magnetic and dielectric properties also analyzed. The size-dependent Mg–CuFe2O4 nanostructures exhibit promising sensing properties which ensure them as a potential candidate for humidity sensor applications. The as-burnt and annealed samples both show a humidity response over the humid range of 10–95 %RH. The sample annealed at 900 °C has the highest average sensor response (6.02 MΩ/%RH) among the as-burnt sample (6.38 MΩ/%RH) and annealed sample at 600 °C (7.11 MΩ/%RH).