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Structural, microstructural, and microwave dielectric properties of (Al1-xBx)2Mo3O12 ceramics with low dielectric constant and low dielectric loss for LTCC applications
The (Al1-xBx)2Mo3O12 ceramics with double phases were prepared by solid-phase sintering method at the temperature from 725 to 800 °C for LTCC application. Through XRD pattern and Rietveld refinement analysis, it was confirmed that the (Al1-xBx)2Mo3O12 composition consists of the coexistence of doubl...
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Published in: | Ceramics international 2023-07, Vol.49 (14), p.22690-22701 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The (Al1-xBx)2Mo3O12 ceramics with double phases were prepared by solid-phase sintering method at the temperature from 725 to 800 °C for LTCC application. Through XRD pattern and Rietveld refinement analysis, it was confirmed that the (Al1-xBx)2Mo3O12 composition consists of the coexistence of double phase (the monoclinic structure of the P21/a space group and the orthorhombic structure of the Pnca space group), and the orthorhombic phase was increased with boron substitution. The microwave dielectric properties of the (Al1-xBx)2Mo3O12 ceramic series were impacted by double-phase formation (crystal structure ratio), which increases the densification and grain uniformity. With the boron substitution, the (Al1-xBx)2Mo3O12 ceramic series demonstrate outstanding microwave dielectric properties (εr = 4.04, Q × f = 35870 GHz @ 15 GHz, τƒ = 4.2 ppm/°C) with high relative density (ρrel ≈ 98.84%) and thermal conductivity κ = 0.88 W/m.K for x = 0.3 at 775 °C, indicate that it is a promising candidate for LTCC substrate material. |
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ISSN: | 0272-8842 |
DOI: | 10.1016/j.ceramint.2023.03.233 |