Combinatorial ratiometric strategy for continuously highly sensitive thermometry in transparent germanate glass-ceramic containing upconversion nanocrystals

• Published in: Ceramics international 2023-12, Vol.49 (23), p.39259-39268
• Main Authors: Luo, Jie, Xiao, Zhuohao, Zeng, Lingwei, He, Chenbo, Liu, Jing, Li, Guannan, Li, Chunmei, He, Hong, Zhou, Lei, Yang, Jun, Tang, Jianfeng
• Format: Article
• Language: English
• Subjects: Germanate glass-ceramic; NaY3F10 nanocrystal; Ratiometric luminescence thermometry; Upconversion luminescence
• ISSN: 0272-8842
• DOI: 10.1016/j.ceramint.2023.09.269

Ratiometric luminescence thermometry is a promising method for non-contact and non-invasive thermometry. Maintaining consistently high temperature sensitivity over a wide temperature range is still a challenge for many ratiometric luminescence thermometers. Here, we have developed a novel transparent germanate glass-ceramic containing NaY3F10:Yb3+/Tm3+/Er3+ nanocrystals. The crystalline content of which remained highly stable during a tunable heat treatment process. Compared with glass, the upconversion luminescence of the glass-ceramic, which originated from the thermally and non-thermally coupled energy levels of Tm3+ and Er3+, was significantly enhanced. Using the temperature-dependent fluorescence intensity ratios of selected upconversion emissions, a ratiometric thermometry scheme with high temperature sensitivity was constructed. The relative sensitivity maintained at a high level (1.30–2.61 %K−1) over the experimental temperature range (323–573 K). The best resolution and repeatability were ±0.13 K and 99.6%, respectively. This transparent glass-ceramic is an excellent candidate for ratiometric thermometry, which is expected to be applied to fibre-optic thermometers.