Combined TL and EPR study to elucidate the origin of luminescent emission from La-doped CaF2 phosphor

• Published in: Ceramics international 2024-10, Vol.50 (19), p.35677-35687
• Main Authors: Mosqueira-Yauri, Jessica, Rao, T.K. Gundu, Rivera-García, Joel A., Huahuasoncco, Klinton V.T., Ayala-Arenas, Jorge S., Benavente, J.F., Rondán-Flores, L.M., Chubaci, José F.D., Cano, Nilo F.
• Format: Article
• Language: English
• Subjects: Defect centers; EPR; La-doped CaF2 phosphor; Luminescence
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2024.06.385

This paper presents the results of the combined study of the thermoluminescence (TL) and electron paramagnetic resonance (EPR) properties of La-doped CaF2 (CaF2: La) phosphor. X-ray diffraction (XRD) results confirmed that CaF2 has been successfully synthesized. Scanning electron microscopy (SEM) results and energy dispersive spectrometer (EDS) spectra show that the synthesized phosphor is pure and has a good overall morphology. The glow curve of CaF2: La phosphor shows an emission band between 230 and 500 nm centered at 340 nm. The Tm-Tstop method and the deconvolution technique were used to find the number of overlapping TL peaks in the 50–300 °C region and their kinetic parameters. A linear dose-response curve was obtained for the range 1–9 Gy, with the onset of a slight supralinear behavior for doses higher than 9 Gy. Gamma-irradiated CaF2: La phosphor has been studied using the technique of EPR to identify the defect centers and also to infer the centers involved in the TL process. Thermal annealing studies indicate the presence of three defect centers. One of the centers (center I) is identified as the O2− ion and is characterized by an axial g-tensor with principal values g∥ = 2.013 and g⊥ = 2.0053. This center correlates with the TL peak at 200 °C. Center II with an isotropic g-value of 2.0005 is attributed to an F center and also relates to the 200 °C TL peak. The third center (center III) is assigned to an F center.