Fabrication and characterization of blue nano ceramic-inks: Utilization of cobalt aluminate pigments prepared by solid state method

The current study focuses on the development and fabrication of ceramic nano inks with improved properties. Firstly, two types of pigments were prepared through a solid state process using fine gibbsite (Al(OH)3) or aluminum chloride (AlCl3) with cobalt chloride hexahydrate (CoCl2.6H2O). The stoichi...

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Bibliographic Details
Published in:Ceramics international 2024-11, Vol.50 (22), p.44943-44956
Main Authors: Ghanaym, E.E., Sadek, H.E.H., El Defrawy, S.A., Abdel-Shafi, A.A., Zawrah, M.F.
Format: Article
Language:English
Subjects:
Cobalt aluminate spinel
Nano ceramic ink
Pigment
Rheology
Sedimentation
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Summary:The current study focuses on the development and fabrication of ceramic nano inks with improved properties. Firstly, two types of pigments were prepared through a solid state process using fine gibbsite (Al(OH)3) or aluminum chloride (AlCl3) with cobalt chloride hexahydrate (CoCl2.6H2O). The stoichiometric precursors were well-mixed and fired at 1000oC; then milled by a high energy ball mill to obtain nano pigments. The prepared pigments were investigated for their phase composition and crystallite size by X-ray diffraction, and further confirmed by Fourier Transform Infrared (FTIR). The morphology and particle size were examined using a scanning electron microscope. The optical properties in terms of UV–Vis, photoluminence emission spectra and CIE chromaticity diagram were also tested. The chemical-state of cobalt and surface elemental composition of prepared Co-aluminate pigments were tested by X-ray photoelectron spectroscopy (XPS). Four groups of ceramic-inks (twelve formulations) were prepared using different percentages of cobalt aluminate pigments and additives. The fabricated inks were investigated for their morphology, rheology, contact-angle and sedimentation behavior. The results revealed that two cobalt aluminate pigments with spinel structure, nano sized particles and blue color, were successfully prepared by the proposed method. The results of optical properties indicated that the cobalt ions are located mainly in tetrahedral sites with a small amount in octahedral sites. The prepared pigments were successfully used in the fabrication of ceramic nano inks with improved properties. The viscosity of most fabricated inks was in the range needed for the industry (4–40 mPa s).
ISSN:0272-8842
DOI:10.1016/j.ceramint.2024.08.332