U-Th/He systematics of fluid-rich ‘fibrous’ diamonds – Evidence for pre- and syn-kimberlite eruption ages

• Published in: Chemical geology 2019-06, Vol.515, p.22-36
• Main Authors: Timmerman, Suzette, Yeow, Hanling, Honda, Masahiko, Howell, Daniel, Jaques, A. Lynton, Krebs, Mandy Y., Woodland, Sarah, Pearson, D. Graham, Ávila, Janaína N., Ireland, Trevor R.
• Format: Article
• Language: English
• Subjects: Dating; Diamond; Fluid inclusions; Nitrogen aggregation; Trace elements; U-Th/He systematics
• ISSN: 0009-2541; 1872-6836
• DOI: 10.1016/j.chemgeo.2019.04.001

The physical characteristics and impermeability of diamonds allow them to retain radiogenic 4He produced in-situ from radioactive decay of U, Th and Sm. This study investigates the U-Th/He systematics of fibrous diamonds and provides a first step in quantification of the uncertainties associated with determining the in-situ produced radiogenic 4He concentration. Factors determining the total amount of measured helium in a diamond are the initial trapped 4He, the in-situ produced radiogenic 4He, α-implantation, α-ejection, diffusion, and cosmogenic 3He production. Alpha implantation is negligible, and diffusion is slow, but the cosmogenic 3He component can be significant for alluvial diamonds as the recovery depth is unknown. Therefore, samples were grouped based on similar major and trace element compositions to determine possible genetically related samples. A correlation between the 4He and U-Th concentrations approximates the initial 4He concentration at the axis-intersect and age as the slope. In this study, the corrections were applied to eight fibrous cubic diamonds from the Democratic Republic of the Congo and two diamonds from the Jwaneng kimberlite in Botswana. A correlation exists between the 4He and U-Th concentrations of the group ZRC2, 3, and 6, and of the group CNG2, 3, and 4 and both correlations deviate significantly from a 71 Ma kimberlite eruption isochron. The U-Th/He dating method appears a promising new approach to date metasomatic fluid events that result in fibrous diamond formation and this is the first evidence that some fibrous diamonds can be formed 10s to 100s Myr before the kimberlite eruption. •Quantification of initial trapped 4He, in-situ produced radiogenic 4He, α-implantation, and α-ejection.•Comparing crushing and heating experiments shows crushing does not efficiently release 4He from fibrous diamond.•U-Th/He model ages and isochronous correlations indicate fibrous diamonds can form 10s–100s Myr before kimberlite eruption.