Cold-seep carbonates of the Laptev Sea continental slope: Constraints from fluid sources and environment of formation

• Published in: Chemical geology 2022-11, Vol.610, p.121103, Article 121103
• Main Authors: Ruban, Alexey, Rudmin, Maxim, Mazurov, Alexey, Chernykh, Denis, Dudarev, Oleg, Semiletov, Igor
• Format: Article
• Language: English
• Subjects: Authigenic carbonates; Cold seep; Laptev Sea; Redox conditions; Stable oxygen and carbon isotopes; Trace element enrichments
• ISSN: 0009-2541; 1872-6836
• DOI: 10.1016/j.chemgeo.2022.121103

This study presents results of the petrographic, mineralogical, stable isotopes of oxygen and carbon, and trace element investigation of authigenic carbonates collected at newly discovered active cold seeps on the Laptev Sea continental slope at ∼300 m water depth. These carbonates are mainly represented by Mg-calcite with MgCO3 content from 9.1 mol% to 14.0 mol%. The low δ13C values of carbonates ranging from −50.6 ‰ to −32.4 ‰ (V-PDB) indicate that they were formed from anaerobic oxidation of biogenic methane and minor participation of other carbon sources. The difference between measured (from 4.7 ‰ to 5.5 ‰) and calculated (4.0 ‰) δ18Ocarb values might be inherited from fluids enriched in 18O due to dissociation of gas hydrates, which could be the source of methane. The carbonates exhibit weak enrichment in Co, moderate and strong enrichments in As, Mo, and Sb, and strong enrichment in U. Interestingly, As, Sb, and Co correlate with the pyrite content. This indicates that authigenic iron sulfides promote the immobilization of these redox-sensitive elements in seep sediments. The (Mo/U)EF values and anomalies of concentration of Mo and U probably indicate variations in the redox conditions during carbonate formation due to episodically seepage activity changes. Ascending methane-bearing fluids were the main contributor to the enrichment of cold-seep carbonates in As, Mo, Sb, and U at the Laptev Sea continental slope. However additional input from the particulate shuttle process can not be ruled out. •Cold-seep carbonates from Laptev Sea continental slope are mainly represented by high-magnesium calcite.•High-magnesian calcite formed from anaerobic oxidation of biogenic methane and minor participation of other carbon sources.•Carbonates are enriched by As, Mo, Sb, and U.•Ascending methane fluids are the main contributor to the enrichment of cold-seep carbonates by trace elements.