Heteroatom-doped magnetic hydrochar to remove post-transition and transition metals from water: Synthesis, characterization, and adsorption studies

• Published in: Chemosphere (Oxford) 2019-03, Vol.218, p.1089-1099
• Main Authors: Khan, Moonis Ali, Alqadami, Ayoub Abdullah, Otero, Marta, Siddiqui, Masoom Raza, Alothman, Zeid Abdullah, Alsohaimi, Ibrahim, Rafatullah, M., Hamedelniel, Abdelrazig Elfaki
• Format: Article
• Language: English
• Subjects: Hydrothermal carbonization; Magnetization; Nitrogen-doping; Sugarcane bagasse; Water treatment
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2018.11.210

Efforts to improve water quality have led to the development of green and sustainable water treatment approaches. Herein, nitrogen-doped magnetized hydrochar (mSBHC-N) was synthesized, characterized, and used for the removal of post-transition and transition heavy metals, viz. Pb2+ and Cd2+ from aqueous environment. mSBHC-N was found to be mesoporous (BET surface area – 62.5 m2/g) and paramagnetic (saturation magnetization – 44 emu/g). Both, FT-IR (with peaks at 577, 1065, 1609 and 3440 cm−1 corresponding to Fe – O stretching vibrations, C – N stretching, N – H in-plane deformation and stretching) and XPS analyses (with peaks at 284.4, 400, 530, 710 eV due to C 1s, N 1s, O 1s, and Fe 2p) confirmed the presence of oxygen and nitrogen containing functional groups on mSBHC-N. The adsorption of Pb2+ and Cd2+ was governed by oxygen and nitrogen functionalities through electrostatic and co-ordination forces. 75–80% of Pb2+ and Cd2+ adsorption at Co: 25 mg/L, either from deionized water or humic acid solution was accomplished within 15 min. The data was fitted to pseudo-second-order kinetic and Langmuir isotherm models, with maximum monolayer adsorption capacities being 323 and 357 mg/g for Cd2+and Pb2+ at 318 K, respectively. Maximum Cd2+ (82.6%) and Pb2+ (78.7%) were eluted with 0.01 M HCl, simultaneously allowing minimum iron leaching (2.73%) from mSBHC-N. In conclusion, the study may provide a novel, economical, and clean route to utilize agro-waste, such as sugarcane bagasse (SB), for aquatic environment remediation. [Display omitted] •Waste sugarcane bagasse was used as precursor to produce hydrochar (SBHC).•SBHC was magnetized and functionalized to N-doped magnetized hydrochar (mSBHC-N).•mSBHC-N was characterized by XRD, FT-IR, SEM-EDX, VSM, XPS, TEM and BET analysis.•mSBHC-N showed fast and high Pb2+ (357 mg/g) and Cd2+ (323 mg/g) uptake.•Electrostatic and co-ordination forces played a foremost role in metals adsorption.