Luminescence in collision-induced dissociation of ND3 by H+, H2+, and H3+ beams at energies below 1000eV

[Display omitted] The luminescence of ND radical and hydrogen Balmer series has been observed in the collisions of Hn+ (n=1, 2, 3) ions with ND3. Absolute luminescence cross sections, excitation functions, as well as electronic ND(c–a)/ND(A–X) and Dβ/Hβ branching ratios were determined. The rotation...

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Bibliographic Details
Published in:Chemical physics 2017-02, Vol.483-484, p.78-83
Main Authors: Drozdowski, R., Werbowy, S., Kowalski, A., Pranszke, B.
Format: Article
Language:English
Subjects:
Cross sections
Ion beams
Luminescence
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Summary:[Display omitted] The luminescence of ND radical and hydrogen Balmer series has been observed in the collisions of Hn+ (n=1, 2, 3) ions with ND3. Absolute luminescence cross sections, excitation functions, as well as electronic ND(c–a)/ND(A–X) and Dβ/Hβ branching ratios were determined. The rotational and vibrational temperatures characterizing populations of the ND∗(A3Π,c1Π) states were estimated from computer simulations of the spectra.
ISSN:0301-0104
DOI:10.1016/j.chemphys.2016.10.013