Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: A review

• Published in: Advances in colloid and interface science 2008-08, Vol.140 (2), p.114-131
• Main Authors: Bhattacharyya, Krishna Gopal, Gupta, Susmita Sen
• Format: Article
• Language: English
• Subjects: Adsorption; Chemistry; Colloidal state and disperse state; Electrochemistry; Exact sciences and technology; General and physical chemistry; Heavy metals; Kaolinite; Membranes; Modified clay; Montmorillonite; Surface physical chemistry
• ISSN: 0001-8686; 1873-3727
• DOI: 10.1016/j.cis.2007.12.008

The feasibility of using two important and common clay minerals, kaolinite and montmorillonite, as adsorbents for removal of toxic heavy metals has been reviewed. A good number of works have been reported where the modifications of these natural clays were done to carry the adsorption of metals from aqueous solutions. The modification was predominantly done by pillaring with various polyoxy cations of Zr 4+, Al 3+, Si 4+, Ti 4+, Fe 3+, Cr 3+or Ga 3+, etc. Preparation of pillared clays with quaternary ammonium cations, namely, tetramethylammonium-, tetramethylphosphonium- and trimethyl-phenylammonium-, N′-didodecyl-N, N′-tetramethylethanediammonium, etc, are also common. Moreover, the acid treatment of clays often boosted their adsorption capacities. The adsorption of toxic metals, viz., As, Cd, Cr, Co, Cu, Fe, Pb, Mn, Ni, Zn, etc., have been studied predominantly. Montmorillonite and its modified forms have much higher metal adsorption capacity compared to that of kaolinite as well as modified-kaolinite.