Modification and sequential treatment of EU-1 zeolite in mild alkali and alkaline-acid conditions

• Published in: Chinese journal of chemical engineering 2016-12, Vol.24 (12), p.1728-1734
• Main Authors: Li, Xiaofeng, Sun, Xiaotao, Zhang, Yanting, Zhang, Junliang, Ren, Pengchao, Liu, Xiaozhen, Dou, Tao
• Format: Article
• Language: English
• Subjects: Catalysis; EU-1 zeolite; Mesoporous
• ISSN: 1004-9541; 2210-321X
• DOI: 10.1016/j.cjche.2016.08.020

EU-1 zeolites were sequentially treated with low-concentration sodium carbonate（Na_2CO_3） and hydrochloric acid（HCl） solutions.The obtained samples were characterized by X-ray diffraction（XRD）,scanning electron microscopy（SEM）,N_2 adsorption/desorption,temperature programmed desorption of NH_3（NH_3-TPD）,solid state~（27）A1 nuclear magnetic resonance（~（27）A1 NMR）,and the catalytic performances of the treated samples were tested in the xylene isomerization reaction.The results showed that the external surface area and mesoporous volume of the sample sequentially treated with 0.05 mol·L~（-1） Na_2CO_3 and 0.1 mol·L~（-1） HCl solutions reached73.9 m~2·g~（-1） and 0.162 cm~3·g~（-1）,respectively.The catalytic performances of EU-1 zeolites were significantly improved,that the activity of the probe reaction increased from 23.03%to 23.61%and the selectivity increased from85.09%to 87.14%compared with those of parent sample.Furthermore,it was found that only amorphous silica and alumina species was dissolved during the post-treatment process,but the framework structure and the acidic properties of EU-1 zeolite remained intact.