Treatment of clay with KF: New solid catalyst for biodiesel production

• Published in: Applied clay science 2014-04, Vol.91-92, p.98-104
• Main Authors: Alves, H.J., da Rocha, A.M., Monteiro, M.R., Moretti, C., Cabrelon, M.D., Schwengber, C.A., Milinsk, M.C.
• Format: Article
• Language: English
• Subjects: Biodiesel; Biomass conversion; Earth sciences; Earth, ocean, space; Exact sciences and technology; Heterogeneous catalysis; Impregnation; Mineralogy; Silicates; Smectite
• ISSN: 0169-1317; 1872-9053
• DOI: 10.1016/j.clay.2014.02.004

A novel solid catalyst with basic properties was developed from untreated smectite chemically modified by treatment with potassium fluoride, resulting in a material with excellent stability and high catalytic activity in the conversion of soybean oil into biodiesel in the presence of methyl alcohol. The percentage of conversion into methyl esters of 99.7% was obtained under conditions of 1h of reaction time at 338K, 15wt.% catalyst and molar ratio of methanol/oil of 6:1. A concomitant study was made to evaluate the effect of the mineralogical composition of the untreated clay on the properties of the catalysts and their performance in the transesterification reaction. [Display omitted] •A novel catalyst was developed from clay by treatment with KF.•The treatment resulted in the formation of crystalline phase K2FeF4.•Test of activity in the methanolysis of soybean oil for the synthesis of biodiesel•Conversion rates of 99.7% were reached in reaction conditions considered mild.•A basic catalyst with high stability was obtained.