Joint kinetics: a new paradigm for chemical kinetics and chemical engineering

Joint kinetics, a new paradigm for chemical kinetics and chemical engineering, is proposed. Its main idea is performing a battery of kinetic experiments from special initial compositions accompanied by the analysis of the information obtained. Within the developed theory, new basic concepts are pres...

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Bibliographic Details
Published in:Current opinion in chemical engineering 2020-09, Vol.29, p.83-88
Main Authors: Yablonsky, Gregory S, Constales, Denis, Marin, Guy B
Format: Article
Language:English
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Summary:Joint kinetics, a new paradigm for chemical kinetics and chemical engineering, is proposed. Its main idea is performing a battery of kinetic experiments from special initial compositions accompanied by the analysis of the information obtained. Within the developed theory, new basic concepts are presented: events and maps of events; new invariances, thermodynamic and non-thermodynamic; perturbed equilibria, conservatively perturbed equilibrium and swapped equilibrium. Joint kinetics can be considered as an efficient tool for revealing the detailed mechanism and determining the kinetic coefficients of complex reactions.
ISSN:2211-3398
2211-3398
DOI:10.1016/j.coche.2020.06.007