Preparation and characteristics of core–shell structure nickel/silica nanoparticles

• Published in: Colloids and surfaces. A, Physicochemical and engineering aspects Physicochemical and engineering aspects, 2005-07, Vol.262 (1), p.71-75
• Main Authors: Fu, Wuyou, Yang, Haibin, Chang, Lianxia, Li, Minghui, Bala, Hari, Yu, Qingjiang, Zou, Guangtian
• Format: Article
• Language: English
• Subjects: Chemistry; Colloidal gels. Colloidal sols; Colloidal state and disperse state; Core–shell; Exact sciences and technology; General and physical chemistry; Nanoparticles; Nickel/silica; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Sol–gel; Wire electrical explosion
• ISSN: 0927-7757; 1873-4359
• DOI: 10.1016/j.colsurfa.2005.03.028

The spherical nickel nanoparticles (an average diameter of 75 nm) were prepared by wire electrical explosion method, and silica was coated on nickel forming complete coverage by the controlled hydrolysis and condensation of tetraethyl orthosilicate (TEOS). The method was based on the use of silane coupling agent 3-mercaptopropyltrimethoxysilane (HS-(CH 2) 3Si(OCH 3) 3, MPTS) as a primer to render the nickel surface vitreophilic, thus rendering nickel surface compatible with silica. The thickness of SiO 2 coating layer increases with the increasing reaction time. The nickel nanoparticles and the nickel coated with silica shell were confirmed by transmission electron microscopy (TEM). X-ray photoelectron spectroscopy (XPS) was used to gain insight into the way in which the MPTS is bound to surface of the nickel nanoparticles. Result of the thermogravimetric analysis (TGA) and differential thermal analysis (DTA) indicate that the thermal stability of nickel/silica is better than of pure nickel nanoparticles. Magnetic properties of these powders have been evaluated. These nickel/silica core–shell nanoparticles can be utilized as precursors for making property-tunable magnetic nanoparticles, thin films, and multilayered core–shell structure nanocomposites.