Investigation on novel redox-responsive ferrocenyl surfactants with reversible interfacial behavior and their recycling application for enhanced oil recovery

• Published in: Colloids and surfaces. A, Physicochemical and engineering aspects Physicochemical and engineering aspects, 2022-11, Vol.653, p.129971, Article 129971
• Main Authors: Jia, Han, He, Juan, Wang, Qiuxia, Xu, Yingbiao, Zhang, Lingyu, Jia, Haidong, Song, Lin, Wang, Yuanbo, Xie, Qiuyu, Wu, Hongyan
• Format: Article
• Language: English
• Subjects: Double-tailed ferrocenyl surfactants; EOR; Interfacial activity; Redox trigger; Supramolecular assembly
• ISSN: 0927-7757; 1873-4359
• DOI: 10.1016/j.colsurfa.2022.129971

Stimuli responsive surfactants with reversible properties may effectively solve the problems of traditional surfactants (the switching of interfacial activity and the demulsification difficulty of emulsions) in enhanced oil recovery (EOR). In the present study, we fabricate brand-new redox-responsive double-tailed ferrocenyl surfactants 1,1′-ferrocenedicarboxylic acid-(N,N-dimethyldodecylamine)2 (FDA-(DMDA)2) via the dynamic supramolecular assembly. The reversible redox-responsive interfacial behaviors of ferrocenyl surfactants are estimated by measuring the interfacial tension reduction capacity, emulsifying performance, and wettability reversal ability. Compared with oxidized single-tailed ferrocenyl surfactant (FA-DMDA-Ox), oxidized double-tailed ferrocenyl surfactant (FDA-(DMDA)2-Ox) displays higher interfacial activity, which can be accurately switched by redox trigger. Cyclic micromodel flooding tests show that the FDA-(DMDA)2-Ox can in-situ emulsify the kerosene in pore media, and the addition of Na2SO3 to the produced fluid can achieve the recycle of the surfactants. Oil displacement tests demonstrate that the developed double-tailed ferrocenyl surfactants possess the potential in EOR and recycling. [Display omitted] •Double-tailed ferrocenyl surfactants are fabricated via supramolecular assembly.•Double-tailed ferrocenyl surfactants show high interfacial activity.•The interfacial activity of surfactants can be switched by redox trigger.•The oxidized ferrocenyl surfactants can vastly enhance tertiary oil recovery.•The redox response can achieve the recycling of ferrocenyl surfactants.