The effect of the changes in chemical composition due to thermal treatment on the mechanical properties of Pinus densiflora

• Published in: Construction & building materials 2022-12, Vol.358, p.129303, Article 129303
• Main Authors: Peng, Qiushi, Ormondroyd, Graham, Spear, Morwenna, Chang, Wen-Shao
• Format: Article
• Language: English
• Subjects: FTIR; Wood Chemical Composition; Wood Mechanical Properties; Wood Thermal-Treatment
• ISSN: 0950-0618; 1879-0526
• DOI: 10.1016/j.conbuildmat.2022.129303

•Timber’s chemical compositions have high correlation to the mechanical properties.•Different thermal treatment environments lead to different changes in timber molecule.•FTIR is a good method to predict timber’s mechanical properties. Wood’s chemical composition has a close relationship to its mechanical properties. Therefore, chemical analysis such as FTIR spectroscopy offers a reasonable non-destructive method to predict wood strength. Pine (Pinus densiflora) specimens were thermal-treated in different conditions (aerobic and anaerobic) and evaluated by 3-point bending test for modulus of rupture (MOR) and by FTIR spectroscopy for chemical composition. Density and moisture content changes were also assessed in this study. The result showed that both density and equilibrium moisture content at 20 °C with 65 % humidity change little at low treatment temperatures, but they decrease at high treatment temperatures and when treated in the presence of oxygen. The MOR was improved by the reactions that occurred, including cellulose crystallisation, lignin condensation and cross-linking, whereas it was decreased by degradation reactions. The MOR were well predicted by two FTIR peak at 1318 cm−1 (relating to CH2 bond and condensation of G-ring of lignin), and at 1730 cm−1 (pertaining to changes to carbonyl groups in hemicelluloses) and density. It was concluded that FTIR spectroscopy provides a suitable method for wood non-destructive mechanical testing.