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Time-resolved morphological study of organic thin film solar cells based on calcium/aluminium cathode material

I n situ time-resolved energy dispersive X-ray reflectometry measurements performed on calcium/aluminium cathode organic solar cells, under working conditions. The stability and degradation of calcium/aluminium cathode organic solar cells are investigated in situ by time-resolved energy dispersive X...

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Bibliographic Details
Published in:Chemical physics letters 2008-08, Vol.461 (1), p.77-81
Main Authors: Paci, B., Generosi, A., Rossi Albertini, V., Perfetti, P., de Bettignies, R., Sentein, C.
Format: Article
Language:English
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Summary:I n situ time-resolved energy dispersive X-ray reflectometry measurements performed on calcium/aluminium cathode organic solar cells, under working conditions. The stability and degradation of calcium/aluminium cathode organic solar cells are investigated in situ by time-resolved energy dispersive X-ray reflectometry. They combine the good charge carrier separation and transport properties of the poly(3-hexylthiophene-2,5-diyl):C 61-butyric acid methyl ester (P3HT:PCBM) bulk heterojunction blend and the capability of the calcium/aluminium cathode to improve the fill factor and the open circuit voltage, with respect to aluminium cathodes cells. The study focuses on the crucial problem of the device structural/morphological stability in working condition. It aims to detect and control possible morphological variations at the various interfaces and to correlate these changes to the device aging.
ISSN:0009-2614
1873-4448
DOI:10.1016/j.cplett.2008.06.070