AC susceptibility analysis on MgB2 bulk and Ti-sheathed wire superconductors

• Published in: Cryogenics (Guildford) 2014-09, Vol.63, p.143-147
• Main Authors: Çiçek, Özlem, Yetiş, Hakan, Gencer, Ali
• Format: Article
• Language: English
• Subjects: AC susceptibility; Boron powder; Magnetization measurements; MgB2 bulk and wire; XRD
• ISSN: 0011-2275; 1879-2235
• DOI: 10.1016/j.cryogenics.2014.07.004

•The effects of the B purity, particle size of Mg, and applied pressure on MgB2.•Larger particle sized Mg powder results in larger FWHM values.•AC susceptibility showed that the purity of B has a significant effect on Tc.•Wire from smaller particle sized Mg powder has higher Fp and Jc. We report a comparative study for bulk MgB2 superconductors and monofilamentary Ti/MgB2 wires as functions of the boron powder purity, average particle size of magnesium, and applied pressure. The structural and magnetic characterizations of the bulk samples were performed by means of XRD and AC susceptibility measurements, respectively. We found that the applied pressure did not cause any significant change on the onset transition temperature Tc,onset and transition width. This is also confirmed by the calculation of the lattice parameters. On the other hand, Tc,onset values were measured as 37.3K, 38.0K, and 38.6K for the samples prepared from the precursor boron powders with purities of 95.2%, ⩾95%, and>98%, respectively. However Mg-particle size (Mg1: AlfaAesar Mg powder, avg. par. size: −325 mesh, purity: 99.8%; Mg2: SigmaAldrich Mg powder, avg. par. size: 20–230 mesh, purity: 98%) did not affect the Tc,onset but increasing the Mg particle size caused a significant broadening at the superconducting transition width for all precursor boron powder purity levels. Magnetization measurements showed that the critical current density of Ti/MgB2 wire prepared from AlfaAesar Mg powder (avg. par. size: −325 mesh) and Aldrich B powder (amorphous, purity⩾95%) is greater than that of prepared by SigmaAldrich Mg powder (avg. par. size: 20–230 mesh) and Pavezyum B powder (amorphous, avg. par. size: 0,3μm (max), purity>98%) as 2.6×105A/cm2 and 1.4×105A/cm2 at T=10K and μ0H=0.5T, respectively. In addition, SigmaAldrich Mg and Pavezyum B wire sample has a lower pinning force, Fp, value at each temperature.