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Effect of CNTs length on thermophysical properties of paraffin/CNTs/graphene aerogel nanocomposite as a shape stabilized phase change material
In this work, paraffin/carbon nanotubes/graphene aerogel (Pa/CNTs/GA) nanocomposite with different CNTs lengths were synthesized. CNTs' length was changed by refluxing them in a mixture of acids for different times, by which the initial micrometer length of CNTs was reduced to 1200 and 205 nm a...
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Published in: | Diamond and related materials 2024-02, Vol.142, p.110746, Article 110746 |
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description | In this work, paraffin/carbon nanotubes/graphene aerogel (Pa/CNTs/GA) nanocomposite with different CNTs lengths were synthesized. CNTs' length was changed by refluxing them in a mixture of acids for different times, by which the initial micrometer length of CNTs was reduced to 1200 and 205 nm after 0.5 and 1 h refluxing. To complete dispersing CNTs in paraffin, they were functionalized for the second time using dodecylamine. By inserting paraffin composites into the aerogel using vacuum impregnation, the thermal conductivity of the aerogel increases greatly. Melting and freezing latent heat of both samples of graphene aerogel composite containing 0.5 and 1 h refluxed CNTs was reduced compared to that of the pure paraffin and Pa/CNTs composite. The specific heat of the Pa/CNTs/GA composite containing 1 h refluxed CNTs was reduced compared to that of the Pa/CNTs (1 h refluxed) composite, but it was increased for the samples containing 0.5 h refluxed CNTs. Also, Pa/ZnO, Pa/TiO2, and Pa/Al2O3 composites were prepared and their thermophysical properties were compared with those of Pa/CNTs composites.
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•Pa/CNTs/GA composites with different CNTs lengths were synthesized.•Thermal conductivity of Pa/GA increased up to about 7 times of GA.•Fusion latent heat of Pa/CNTs/GA was reduced comparing with pure paraffin.•Solidifying latent heat of Pa/CNTs/GA was reduced comparing with pure paraffin.•The specific heat of the Pa/CNTs/GA was less than that of the Pa/CNTs. |
doi_str_mv | 10.1016/j.diamond.2023.110746 |
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[Display omitted]
•Pa/CNTs/GA composites with different CNTs lengths were synthesized.•Thermal conductivity of Pa/GA increased up to about 7 times of GA.•Fusion latent heat of Pa/CNTs/GA was reduced comparing with pure paraffin.•Solidifying latent heat of Pa/CNTs/GA was reduced comparing with pure paraffin.•The specific heat of the Pa/CNTs/GA was less than that of the Pa/CNTs.</description><identifier>ISSN: 0925-9635</identifier><identifier>EISSN: 1879-0062</identifier><identifier>DOI: 10.1016/j.diamond.2023.110746</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Latent heat ; Pa/GA composite ; Paraffin ; Specific heat ; Thermal conductivity</subject><ispartof>Diamond and related materials, 2024-02, Vol.142, p.110746, Article 110746</ispartof><rights>2023 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c309t-710371e1d932159dc63188ff91349fd6d85a7fe409574b743cd39406b397d9c03</citedby><cites>FETCH-LOGICAL-c309t-710371e1d932159dc63188ff91349fd6d85a7fe409574b743cd39406b397d9c03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Farbod, Mansoor</creatorcontrib><creatorcontrib>Mojtahedi, Fateme Sadat</creatorcontrib><creatorcontrib>Ahangarpour, Ameneh</creatorcontrib><title>Effect of CNTs length on thermophysical properties of paraffin/CNTs/graphene aerogel nanocomposite as a shape stabilized phase change material</title><title>Diamond and related materials</title><description>In this work, paraffin/carbon nanotubes/graphene aerogel (Pa/CNTs/GA) nanocomposite with different CNTs lengths were synthesized. CNTs' length was changed by refluxing them in a mixture of acids for different times, by which the initial micrometer length of CNTs was reduced to 1200 and 205 nm after 0.5 and 1 h refluxing. To complete dispersing CNTs in paraffin, they were functionalized for the second time using dodecylamine. By inserting paraffin composites into the aerogel using vacuum impregnation, the thermal conductivity of the aerogel increases greatly. Melting and freezing latent heat of both samples of graphene aerogel composite containing 0.5 and 1 h refluxed CNTs was reduced compared to that of the pure paraffin and Pa/CNTs composite. The specific heat of the Pa/CNTs/GA composite containing 1 h refluxed CNTs was reduced compared to that of the Pa/CNTs (1 h refluxed) composite, but it was increased for the samples containing 0.5 h refluxed CNTs. Also, Pa/ZnO, Pa/TiO2, and Pa/Al2O3 composites were prepared and their thermophysical properties were compared with those of Pa/CNTs composites.
[Display omitted]
•Pa/CNTs/GA composites with different CNTs lengths were synthesized.•Thermal conductivity of Pa/GA increased up to about 7 times of GA.•Fusion latent heat of Pa/CNTs/GA was reduced comparing with pure paraffin.•Solidifying latent heat of Pa/CNTs/GA was reduced comparing with pure paraffin.•The specific heat of the Pa/CNTs/GA was less than that of the Pa/CNTs.</description><subject>Latent heat</subject><subject>Pa/GA composite</subject><subject>Paraffin</subject><subject>Specific heat</subject><subject>Thermal conductivity</subject><issn>0925-9635</issn><issn>1879-0062</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkM1KAzEUhYMoWKuPIOQFpk0m89OsREr9gaKbug63yU0nZSYJySDUh_CZbWn3ri4c7nc4fIQ8cjbjjDfz_cw4GII3s5KVYsY5a6vmikz4opUFY015TSZMlnUhG1Hfkruc94zxUlZ8Qn5X1qIeabB0-bHJtEe_GzsaPB07TEOI3SE7DT2NKURMo8N8-o2QwFrn5ydovksQO_RIAVPYYU89-KDDEEN24zHNFGjuICLNI2xd737Q0NhBRqo78DukA4yYHPT35MZCn_Hhcqfk62W1Wb4V68_X9-XzutCCybFoORMtR26kKHktjW4EXyyslVxU0prGLGpoLVZM1m21bSuhjZAVa7ZCtkZqJqakPvfqFHJOaFVMboB0UJypk1S1Vxep6iRVnaUeuaczh8dx3w6Tytqh12hcOmpUJrh_Gv4A18CE8A</recordid><startdate>202402</startdate><enddate>202402</enddate><creator>Farbod, Mansoor</creator><creator>Mojtahedi, Fateme Sadat</creator><creator>Ahangarpour, Ameneh</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>202402</creationdate><title>Effect of CNTs length on thermophysical properties of paraffin/CNTs/graphene aerogel nanocomposite as a shape stabilized phase change material</title><author>Farbod, Mansoor ; Mojtahedi, Fateme Sadat ; Ahangarpour, Ameneh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c309t-710371e1d932159dc63188ff91349fd6d85a7fe409574b743cd39406b397d9c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Latent heat</topic><topic>Pa/GA composite</topic><topic>Paraffin</topic><topic>Specific heat</topic><topic>Thermal conductivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Farbod, Mansoor</creatorcontrib><creatorcontrib>Mojtahedi, Fateme Sadat</creatorcontrib><creatorcontrib>Ahangarpour, Ameneh</creatorcontrib><collection>CrossRef</collection><jtitle>Diamond and related materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Farbod, Mansoor</au><au>Mojtahedi, Fateme Sadat</au><au>Ahangarpour, Ameneh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of CNTs length on thermophysical properties of paraffin/CNTs/graphene aerogel nanocomposite as a shape stabilized phase change material</atitle><jtitle>Diamond and related materials</jtitle><date>2024-02</date><risdate>2024</risdate><volume>142</volume><spage>110746</spage><pages>110746-</pages><artnum>110746</artnum><issn>0925-9635</issn><eissn>1879-0062</eissn><abstract>In this work, paraffin/carbon nanotubes/graphene aerogel (Pa/CNTs/GA) nanocomposite with different CNTs lengths were synthesized. CNTs' length was changed by refluxing them in a mixture of acids for different times, by which the initial micrometer length of CNTs was reduced to 1200 and 205 nm after 0.5 and 1 h refluxing. To complete dispersing CNTs in paraffin, they were functionalized for the second time using dodecylamine. By inserting paraffin composites into the aerogel using vacuum impregnation, the thermal conductivity of the aerogel increases greatly. Melting and freezing latent heat of both samples of graphene aerogel composite containing 0.5 and 1 h refluxed CNTs was reduced compared to that of the pure paraffin and Pa/CNTs composite. The specific heat of the Pa/CNTs/GA composite containing 1 h refluxed CNTs was reduced compared to that of the Pa/CNTs (1 h refluxed) composite, but it was increased for the samples containing 0.5 h refluxed CNTs. Also, Pa/ZnO, Pa/TiO2, and Pa/Al2O3 composites were prepared and their thermophysical properties were compared with those of Pa/CNTs composites.
[Display omitted]
•Pa/CNTs/GA composites with different CNTs lengths were synthesized.•Thermal conductivity of Pa/GA increased up to about 7 times of GA.•Fusion latent heat of Pa/CNTs/GA was reduced comparing with pure paraffin.•Solidifying latent heat of Pa/CNTs/GA was reduced comparing with pure paraffin.•The specific heat of the Pa/CNTs/GA was less than that of the Pa/CNTs.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.diamond.2023.110746</doi></addata></record> |
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subjects | Latent heat Pa/GA composite Paraffin Specific heat Thermal conductivity |
title | Effect of CNTs length on thermophysical properties of paraffin/CNTs/graphene aerogel nanocomposite as a shape stabilized phase change material |
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