Elucidating the role of S-containing structure in carbon-based catalysts towards efficient H2O2 synthesis in seawater

• Published in: Diamond and related materials 2024-08, Vol.147, p.111349, Article 111349
• Main Authors: Li, Jiangpeng, Zhan, Su, He, Qiuchen, Zhang, Chenglin, Jiang, Wenjun, Zhou, Feng
• Format: Article
• Language: English
• Subjects: Anti-deposition of hydroxide precipitation; H2O2 electrosynthesis; Micro-organisms inactivation; Natural seawater; S-doped carbon
• ISSN: 0925-9635; 1879-0062
• DOI: 10.1016/j.diamond.2024.111349

The on-site sustainable electrochemical synthesis of hydrogen peroxide (H2O2) in natural seawater holds significant practical value in the fields of energy storage and environmental treatment. However, the poisoning of the active sites by ions such as Cl−, Ca2+, and Mg2+ in natural seawater significantly inhibits the ORR activity of the catalyst. Herein, the 2e− ORR performance of S, N co-doped carbon materials in natural seawater was investigated, focusing on the anti-Ca2+/Mg2+ poisoning mechanism of S-doped carbon structures. The data indicate a Faradaic efficiency of 94.2 % for H2O2 production, with a yield of 3.52 mol/(gcat h), and an approximate 100 % sterilization of bacteria and inactivation of chlorella within 10 min. S-doped carbon structures demonstrated enhanced H2O adsorption and dissociation properties during the ORR process, optimized the micro-environment of the catalytic interface, effectively inhibited Ca2+ and Mg2+ deposition. Moreover, S-doping altered the N coordination structure, further enhancing the 2e− ORR selectivity of the catalyst. This study demonstrates the high selectivity of 2e− ORR in natural seawater, offering guidance for designing catalysts using in the complex environment and advancing marine energy storage and environmental treatment technologies. [Display omitted] •S-doping enhances the 2e− ORR performance and stability of carbon catalysts in seawater.•S-doped carbon exhibits efficient sterilization and inactivation of chlorella.•S-doped structure modulates the N coordination structure to optimize the 2e− ORR selectivity.•Elucidation of the mechanism of inhibition of Ca2+, Mg2+ deposition by S-doped carbon structures.