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Photoswitching of 5-phenylazopyrimidines in crystalline powders and thin films

Solid-state photoswitching enables the development of smart materials. However, the close packing of molecules and the lack of free volume in this state prevent sterically demanding structural changes induced by irradiation, thereby precluding the use of azobenzene photoswitches. Nevertheless, we re...

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Published in:Dyes and pigments 2022-03, Vol.199, p.110066, Article 110066
Main Authors: Procházková, Eliška, Filo, Juraj, Čechová, Lucie Mužíková, Dračínský, Martin, Císařová, Ivana, Janeba, Zlatko, Kawamura, Izuru, Naito, Akira, Kuběna, Ivo, Nádaždy, Peter, Šiffalovič, Peter, Cigáň, Marek
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cited_by cdi_FETCH-LOGICAL-c306t-9a4d2d9831594ac81d52f15b06f37118e9e502c60946dd9e96c29bfb472395383
cites cdi_FETCH-LOGICAL-c306t-9a4d2d9831594ac81d52f15b06f37118e9e502c60946dd9e96c29bfb472395383
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container_title Dyes and pigments
container_volume 199
creator Procházková, Eliška
Filo, Juraj
Čechová, Lucie Mužíková
Dračínský, Martin
Císařová, Ivana
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Kawamura, Izuru
Naito, Akira
Kuběna, Ivo
Nádaždy, Peter
Šiffalovič, Peter
Cigáň, Marek
description Solid-state photoswitching enables the development of smart materials. However, the close packing of molecules and the lack of free volume in this state prevent sterically demanding structural changes induced by irradiation, thereby precluding the use of azobenzene photoswitches. Nevertheless, we report here the solid-state photoswitching of their derivatives, 5-phenylazopyrimidines, in crystalline powders and in amorphous thin layers. After identifying trans-cis photoisomerization by NMR spectroscopy, we demonstrated the applicability of 5-phenylazopyrimidines for future all-optical switching applications. For this purpose, we prepared thin films by spin-coating and confirmed their solid-state optical switching by optical transmission spectroscopy and their favorable surface topography by atomic force microscopy. Therefore, thin films of 5-phenylazopyrimidines are suitable for on-chip integration for emerging all-optical technologies. [Display omitted] •Azopyrimidine photoswitching in solid state is led by trans-to-cis photoisomerization.•Photoisomerization efficiency differs in crystalline powders and amorphous thin films.•Thin films show suitable properties for on-chip integration in all-optical technology.
doi_str_mv 10.1016/j.dyepig.2021.110066
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subjects Azo dyes
NMR spectroscopy
Solid-state photoswitching
Thin films
title Photoswitching of 5-phenylazopyrimidines in crystalline powders and thin films
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