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Corrole-gold nanoparticles: Synthesis, ground and excited state solvation
The in situ preparation and the full spectroscopic characterization of corrole - gold nanoparticles (AuTPFCS) are reported. The synthetic approach to these nanoconjugates involved the reaction of a mercaptocorrole (TPFCSH) with chloroauric acid under reductive conditions. Fluorescence quantum yields...
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Published in: | Dyes and pigments 2022-05, Vol.201, p.110108, Article 110108 |
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creator | Barata, Joana F.B. Serra, Vanda Vaz Daniel-da-Silva, Ana L. Neves, M. Graça P.M. S. Costa, Sílvia M.B. Cavaleiro, José A.S. Trindade, Tito |
description | The in situ preparation and the full spectroscopic characterization of corrole - gold nanoparticles (AuTPFCS) are reported. The synthetic approach to these nanoconjugates involved the reaction of a mercaptocorrole (TPFCSH) with chloroauric acid under reductive conditions. Fluorescence quantum yields and time resolved lifetimes showed a significant quenching of the mercaptocorrole after its covalent coupling to the gold nanoparticles in acetonitrile and in toluene. Irradiated samples of AuTPFCS with a Nd:YAG laser in toluene solution revealed the distribution of larger nanoparticles from 3.1 to 11 nm viewed by TEM images.
The in situ synthesis and ground and excited state of corrole-gold nanoparticles (AuTPFCS) are reported. [Display omitted] |
doi_str_mv | 10.1016/j.dyepig.2022.110108 |
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The in situ synthesis and ground and excited state of corrole-gold nanoparticles (AuTPFCS) are reported. [Display omitted]</description><subject>Corrole</subject><subject>Gold nanoparticles</subject><subject>Nanoconjugates</subject><subject>Photophysical properties</subject><subject>Solvation</subject><issn>0143-7208</issn><issn>1873-3743</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kM9KAzEYxIMoWKtv4GEfwF3zb83WgyDFaqHgQT2Hb5MvNWXdLEks9u3dsp49DAMDMww_Qq4ZrRhld7e7yh5w8NuKU84rNma0OSEz1ihRCiXFKZlRJkWpOG3OyUVKO0ppIzibkfUyxBg6LLehs0UPfRggZm86TPfF26HPn5h8uim2MXz3toBR-GN8RlukDBmLFLo9ZB_6S3LmoEt49edz8rF6el--lJvX5_XycVMaQVkulZDOSeDWNSigVsBBOEpl3bDaLJhxrVGcc6g5r8G0tWlBMrlA17ZOWcXEnMhp18SQUkSnh-i_IB40o_qIQ-_0hEMfcegJx1h7mGo4ftt7jDoZj71B6yOarG3w_w_8AlN8bAQ</recordid><startdate>202205</startdate><enddate>202205</enddate><creator>Barata, Joana F.B.</creator><creator>Serra, Vanda Vaz</creator><creator>Daniel-da-Silva, Ana L.</creator><creator>Neves, M. Graça P.M. S.</creator><creator>Costa, Sílvia M.B.</creator><creator>Cavaleiro, José A.S.</creator><creator>Trindade, Tito</creator><general>Elsevier Ltd</general><scope>6I.</scope><scope>AAFTH</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-0794-144X</orcidid></search><sort><creationdate>202205</creationdate><title>Corrole-gold nanoparticles: Synthesis, ground and excited state solvation</title><author>Barata, Joana F.B. ; Serra, Vanda Vaz ; Daniel-da-Silva, Ana L. ; Neves, M. Graça P.M. S. ; Costa, Sílvia M.B. ; Cavaleiro, José A.S. ; Trindade, Tito</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c301t-734ff4a2df8e3a57a2a3f0045815c91cfbc7222a5225acb5cba4149efbbf7d713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Corrole</topic><topic>Gold nanoparticles</topic><topic>Nanoconjugates</topic><topic>Photophysical properties</topic><topic>Solvation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Barata, Joana F.B.</creatorcontrib><creatorcontrib>Serra, Vanda Vaz</creatorcontrib><creatorcontrib>Daniel-da-Silva, Ana L.</creatorcontrib><creatorcontrib>Neves, M. Graça P.M. S.</creatorcontrib><creatorcontrib>Costa, Sílvia M.B.</creatorcontrib><creatorcontrib>Cavaleiro, José A.S.</creatorcontrib><creatorcontrib>Trindade, Tito</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>CrossRef</collection><jtitle>Dyes and pigments</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Barata, Joana F.B.</au><au>Serra, Vanda Vaz</au><au>Daniel-da-Silva, Ana L.</au><au>Neves, M. Graça P.M. S.</au><au>Costa, Sílvia M.B.</au><au>Cavaleiro, José A.S.</au><au>Trindade, Tito</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Corrole-gold nanoparticles: Synthesis, ground and excited state solvation</atitle><jtitle>Dyes and pigments</jtitle><date>2022-05</date><risdate>2022</risdate><volume>201</volume><spage>110108</spage><pages>110108-</pages><artnum>110108</artnum><issn>0143-7208</issn><eissn>1873-3743</eissn><abstract>The in situ preparation and the full spectroscopic characterization of corrole - gold nanoparticles (AuTPFCS) are reported. The synthetic approach to these nanoconjugates involved the reaction of a mercaptocorrole (TPFCSH) with chloroauric acid under reductive conditions. Fluorescence quantum yields and time resolved lifetimes showed a significant quenching of the mercaptocorrole after its covalent coupling to the gold nanoparticles in acetonitrile and in toluene. Irradiated samples of AuTPFCS with a Nd:YAG laser in toluene solution revealed the distribution of larger nanoparticles from 3.1 to 11 nm viewed by TEM images.
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subjects | Corrole Gold nanoparticles Nanoconjugates Photophysical properties Solvation |
title | Corrole-gold nanoparticles: Synthesis, ground and excited state solvation |
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