New lithium ion conducting polymer electrolytes based on polysiloxane grafted with Si-tripodand centers

• Published in: Electrochemistry communications 2007-07, Vol.9 (7), p.1558-1562
• Main Authors: Walkowiak, M., Schroeder, G., Gierczyk, B., Waszak, D., Osińska, M.
• Format: Article
• Language: English
• Subjects: Applied sciences; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Exact sciences and technology; Hydrosilylation; Li-ion battery; Podands; Polymer electrolytes; Silanes
• ISSN: 1388-2481; 1873-1902
• DOI: 10.1016/j.elecom.2007.02.019

New kind of polymer host for lithium cations has been synthesized by catalyzed hydrosilylation reaction involving hydrogen atoms of a polysiloxane and double bonds of vinyl tris-2-methoxyethoxy silane. The obtained macromolecule can be regarded as siloxane backbone grafted with silicon tripodand elements with very short polyether chains. A family of Li ion conducting polymer electrolyte membranes have been prepared by dissolving LiPF 6 in thus obtained polymer matrix. Exceptionally high room temperature specific conductivities, exceeding 10 −3 S/cm at 25 °C, have been measured for the studied polymer electrolytes. It is proposed that polyether chains tend to self-assembly in the presence of Li cations and this highly organized arrangement of Li coordination sites creates pathways of high lithium conductivity along the polysiloxane backbones. In addition to that, strong shielding of Li-cations suppresses the formation of ion pairs, thus increasing the charge carrier concentration. The electrolytes can be easily formed into dimensionally stable, flexible membranes.