Effect of Sm3+ content on the properties and electrochemical performance of SmxSr1−xCoO3−δ (0.2≤x≤0.8) as an oxygen reduction electrodes on doped ceria electrolytes

• Published in: Electrochimica acta 2011-02, Vol.56 (7), p.2870-2876
• Main Authors: Guo, Youmin, Chen, Dengjie, Shi, Huangang, Ran, Ran, Shao, Zongping
• Format: Article
• Language: English
• Subjects: Applied sciences; Electrical conductivity; Electrode performance; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Oxygen vacancy concentration; Samarium strontium cobaltite; Thermal expansion
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2010.12.075

SmxSr1−xCoO3−δ (SSCx) materials are promising cathodes for IT-SOFCs. The influence of Sm content in SSCx (0.2≤x≤0.8) oxides on their oxygen nonstoichiometry, oxygen desorption, thermal expansion behavior, electrical conductivity and electrochemical activity for oxygen reduction is systematically studied by iodometric titration, oxygen-temperature programmed desorption (O2-TPD), dilatometer, four-probe DC conductivity, electrochemical impedance spectroscopy (EIS) and three-electrode polarization test, respectively. Iodometric titration experiments demonstrate that the electrical charge neutrality compensation in SSCx proceeds preferably through the oxidation of cobalt ion for high Sm3+ contents (x≥0.6). However, it proceeds mainly through the creation of oxygen vacancies at x≤0.5. O2-TPD shows SSC5 possesses the highest oxygen desorption ability among the range of SSCx materials tested. The thermal expansion coefficients (TECs) are high between the transition temperature and 900°C, showing values typically larger than 20×10−6K−1. All dense materials show high electrical conductivity with a maximum value of ∼1885Scm−1 for SSC6 in air, while SSC5 has the highest electrical conductivity in nitrogen. EIS analysis of porous electrodes demonstrates that SSC5 has the lowest area specific resistance (ASR) value (0.42Ωcm2) at 600°C. Cathodic overpotential testing demonstrates that SSC5 also has the largest exchange current density of 60mAcm−2 at 600°C in air.