Synthesis, stability and conductivity of SrCe0.8-xZrxY0.2O3-δ as electrolyte for proton conducting SOFC

Strontium cerate (SrCeO3) exhibits proton conductivity in humidified atmosphere at elevated temperature. However this material is unstable in CO2 and H2O atmosphere. Thought its proton conductivity is lower than barium cerate (BaCeO3) there is scope to improve its stability, sinterability and ionic...

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Bibliographic Details
Published in:Electrochimica acta 2016-11, Vol.219, p.614-622
Main Authors: Mahadik, Pooja Sawant, Jain, Dheeraj, Shirsat, A.N., Manoj, N., Varma, S., Wani, B.N., Bharadwaj, S.R.
Format: Article
Language:English
Subjects:
Electrolyte
Impedance
Proton conductor
Solid oxide Fuel Cell
Thermogravimetry
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Summary:Strontium cerate (SrCeO3) exhibits proton conductivity in humidified atmosphere at elevated temperature. However this material is unstable in CO2 and H2O atmosphere. Thought its proton conductivity is lower than barium cerate (BaCeO3) there is scope to improve its stability, sinterability and ionic conductivity by substituting suitable cations at B-site. SrCe0.8-xZrxY0.2O3-δ (SCZY, with x=0.0, 0.2, 0.4, 0.6 and 0.8) powders were synthesized by sol gel route. Lattice parameters were generated from powder XRD data and it was found that with increase in Zr content the cell volume reduces. Chemical stability of sintered SCZY samples was evaluated in 100% CO2 using TG-DTA up to 1173K and also in boiling water. Zirconium doped samples exhibit enhanced chemical stability in presence of carbon dioxide and boiling water, with x≥0.4 compositions having no effect of both the reactive gases. Proton conductivity of SCZY samples were measured in moist N2 atmosphere. Activation energy for proton conduction was also evaluated.
ISSN:0013-4686
1873-3859
DOI:10.1016/j.electacta.2016.09.072