Capacitive performance of electrodeposited PEDOS and a comparative study with PEDOT

• Published in: Electrochimica acta 2016-12, Vol.220, p.340-346
• Main Authors: Liu, Hongtao, Zhou, Weiqiang, Ma, Xiumei, Chen, Shuai, Ming, Shouli, Lin, Kaiwen, Lu, Baoyang, Xu, Jingkun
• Format: Article
• Language: English
• Subjects: Electropolymerization; EQCM; PEDOS; PEDOT; Supercapacitor
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2016.10.113

Poly(3,4-ethylenedioxyselenophene) (PEDOS) prepared via electropolymerization was investigated as an active electrode material for supercapacitor in 0.1M CH3CN-LiClO4 and compared with PEDOT under the same conditions. The resultant polymers were characterized by EQCM, FT-IR, SEM, CV, and EIS. Although EDOS possessed higher molar mass which may result in lower specific capacitance in theory, but the higher doping level (y=0.53) make the specific capacitance of PEDOS over that of PEDOT. Based on this, PEDOS have had the potential to become a good supercapacitor material. [Display omitted] •PEDOS was investigated as a novel and active supercapacitor electrode material.•PEDOS film electrode afforded good specific capacitance.•The different capacitive performance between PEDOS and PEDOT were explained. Poly(3,4-ethylenedioxyselenophene) (PEDOS) prepared via electropolymerization was investigated as an active electrode material for supercapacitor in 0.1M CH3CN-LiClO4. Meanwhile, Poly(3,4-ethylenedioxythiophene) (PEDOT) as a contrast was prepared and measured under the same conditions. The resultant polymers were characterized by EQCM, FT-IR, SEM, CV and EIS. Although EDOS possessed higher molar mass which may result in lower specific capacitance in theory, but the higher doping level (y=0.53) make the specific capacitance of PEDOS over that of PEDOT. Based on this, PEDOS has the potential to become a good supercapacitor material. The compact PEDOS electrode afforded a higher specific capacitance of 208Fg−1 at 25mVs−1 compared with PEDOT (205Fg−1). Furthermore, the specific capacitance of the symmetric full cell based on two PEDOS electrodes reached 42.02Fg−1 at 25mVs−1.