Nanosheet-structured NiCoO2/carbon nanotubes hybrid composite as a novel bifunctional oxygen electrocatalyst

• Published in: Electrochimica acta 2017-10, Vol.252, p.338-349
• Main Authors: Ma, Li, Zhou, Han, Sun, Yao, Xin, Shuli, Xiao, Chunhui, Kumatani, Akichika, Matsue, Tomokazu, Zhang, Penghui, Ding, Shujiang, Li, Fei
• Format: Article
• Language: English
• Subjects: Nanosheet structure; NiCoO2/carbon nanotubes composite; Oxygen evolution reaction; Oxygen reduction reaction; Scanning electrochemical microscopy (SECM)
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2017.08.192

Synthesis of novel bifunctional catalysts based on earth-abundant elements with high catalytic activities for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) becomes a main strategy to promote the development of metal-air batteries and fuel cells. Herein, a novel Co2+-based mixed transition metal oxide composite, the three-dimensional (3D) nanosheet-structured NiCoO2/carbon nanotubes (CNTs) composite, was successfully synthesized through a facile one-pot method. The better electrocatalytic activities of NiCoO2/CNTs for both ORR and OER than those of pure NiCoO2, CNTs, physically mixed NiCoO2 and CNTs, and Co3O4/CNTs are proved. The comparison of local ORR and OER electrocatalytic activities of NiCoO2/CNTs to other catalysts are obtained by scanning electrochemical microscopy (SECM) characterizations. The closed oxygen reduction peak and half-wave potentials, nearly four-electron dominated process, better methanol tolerance and electrochemical stability confirm the comparable electrocatalytic performance and better stability of NiCoO2/CNTs to the commercial Pt/C catalyst for ORR. The similar stability of NiCoO2/CNTs demonstrates its comparable electrocatalytic performance to the state-of-the-art RuO2 catalyst for OER. The as-prepared NiCoO2/CNTs composite presents as a promising bifunctional oxygen electrocatalyst in alkaline solution for potential applications.