Polymer enhanced foam for improving oil recovery in oil-wet carbonate reservoirs: A proof of concept and insights into the polymer-surfactant interactions

• Published in: Energy (Oxford) 2023-02, Vol.264, p.126256, Article 126256
• Main Authors: Wu, Qianhui, Ding, Lei, Zhang, Lei, Ge, Jijiang, Rahman, Mohammad Azizur, Economou, Ioannis G., Guérillot, Dominique
• Format: Article
• Language: English
• Subjects: Associative polymer; Enhanced oil recovery; Polymer enhanced foam; Wettability
• ISSN: 0360-5442
• DOI: 10.1016/j.energy.2022.126256

The feasibility of polymer enhanced foam (PEF) for enhanced oil recovery (EOR) in a strongly oil-wet and heterogeneous carbonate reservoir with medium temperature (131 °F) and high salinity was experimentally investigated. An Alkyl Poly-Glycoside (APG) surfactant was firstly selected because of its prominent foam behavior in oil-wet carbonates. The effect of polymer type, flow rate and brine composition on foam strength and stability were systematically investigated, aiming to understand how the interactions between polymer and surfactant could influence the transport behavior and performance of PEF in porous media. It was found that, with either an associative polymer or a nonionic polymer (PAM), the foam strength and foam stability could be largely enhanced, both in the absence and in the presence of oil. A significant improvement in oil recovery efficiency was obtained for PEF with an associative polymer, approximately 5% higher than that achieved for conventional polymer-free foam. The PEF behavior is intimately dependent on the interactions between the polymer and the surfactant. It is hypothesized that the increased foam strength by adding polymer at oil-wet conditions may be resulted from an increase of aqueous phase viscosity, the wettability alteration from oil-wet to less oil-wet, the generation of a highly viscoelastic film and (or) the creation of a more stable pseudo-emulsion film. This study provides a robust approach for PEF mobility control and reservoir conformance in oil-wet and heterogeneous carbonate reservoir under analogous reservoir conditions. [Display omitted] •Polymer Enhanced Foam can improve oil recovery under oil-wet condition.•Foam behavior with an associative polymer and a polyacrylamide is compared.•The viscoelasticity of liquid film is enhanced by adding polymer.•Correlation between the foam behavior in the bulk and porous media is poor.•Surfactant-polymer interactions are pivotal to control the foam strength.