Occurrence of tetrabromobisphenol a (TBBPA) and hexabromocyclododecane (HBCD) in soil and road dust in Chongqing, western China, with emphasis on diastereoisomer profiles, particle size distribution, and human exposure

• Published in: Environmental pollution (1987) 2018-11, Vol.242 (Pt A), p.219-228
• Main Authors: Lu, Jun-Feng, He, Ming-Jing, Yang, Zhi-Hao, Wei, Shi-Qiang
• Format: Article
• Language: English
• Subjects: Hexabromocyclododecane; Human exposure; Particle size distribution; Soil and road dust; Tetrabromobisphenol A
• ISSN: 0269-7491; 1873-6424
• DOI: 10.1016/j.envpol.2018.06.087

Currently, the HBCDs were listed in Annex A by the Stockholm Convention, and the knowledge on the contamination of TBBPA and HBCDs in soil and road dust in China is still limited, and it is unclear what role is played by dust particle size distribution. In this study, a total of 81 soil and 43 road dust samples were analyzed with TBBPA and ΣHBCDs concentrations ranging from < LOQ to 33.8 ng/g dw (dry weight) and 0.43–15.2 ng/g dw in soil, and from < LOQ to 74.1 ng/g dw and 7.25–14.0 ng/g dw in road dust, respectively. TBBPA and HBCDs exhibited different spatial distribution patterns in soil, where relatively high levels of HBCDs were found in industrial area and commercial area, while high levels of TBBPA were detceted in residential area. However, no distinct variation in spatial distribution of these two compounds was observed in road dust. Different diastereoisomer profiles of HBCDs were also found with γ-HBCD predominating in soil and α-HBCD occupying a large proportion in road dust. The α-/γ-HBCD values in road dust were significantly greater (T-test, P