Exploring the influence of varying pH on structural, electro-optical, magnetic and photo-Fenton properties of mesoporous ZnFe2O4 nanocrystals

• Published in: Environmental pollution (1987) 2021-03, Vol.272, p.115983, Article 115983
• Main Authors: Vinosha, P. Annie, Manikandan, A., Ragu, R., Dinesh, A., Paulraj, P., Slimani, Y., Almessiere, M.A., Baykal, A., Madhavan, J., Xavier, Belina, Nirmala, G. Francisco
• Format: Article
• Language: English
• Subjects: Magnetic property; Optical property; Photo- Fenton; Soft magnet; Surface area; ZnFe2O4 nanocrystals
• ISSN: 0269-7491; 1873-6424
• DOI: 10.1016/j.envpol.2020.115983

An economically viable and superficial technique was indorsed to yield ZnFe2O4 nanocrystals in the system to investigate the impact of pH variation on the optical, structural, electrical, and magnetic properties of as-prepared nanocrystals. The as-synthesized ZnFe2O4 nanocrystals were premeditated with the application protracted to degradation of Methylene blue organic dye. The results specify that the pH plays the utmost decisive facet in photo-Fenton recital. From XRD (X-Ray diffraction) analyses, it was confirmed that as-synthesized nanocrystals belong to a cubic Fd3m crystal phase. The crystallite size was also determined by the Scherrer formula and it was noticed that as the pH rises the crystallite size also increased. FT-IR (Fourier Transform Infrared) analysis depicts two absorption peaks ∼ 500 and ∼600 cm−1 that represents tetrahedral (Td) and octahedral (Oh) sites. Using TEM (Transmission Electron Microscopy), the morphology was observed to be spherical particles with some agglomeration. Photoluminescence and UV–visible spectral studies were performed to investigate the optical properties. The bandgap energy was seen to decrease as the pH increased. Using BET analysis, the surface area for the as-synthesized samples was found to decrease on increasing the pH. The reaction results showed that the ZnFe2O4 has good photocatalytic activity, which can be attributed to high surface area and pore volume, and large pore size. The ZnFe2O4 produced by the co-precipitation route exhibited promising photocatalytic activity for the removal of textile dye, reaching nearly 99.2% of decolorization at 100 min. Therefore, ZnFe2O4 particles rapidly prepared by the co-precipitation route have the potential for use in treatment of textile wastewater by the heterogeneous photo-Fenton process. With the help of VSM analysis, the coercivity and other magnetic properties were determined for the as-synthesized nanocrystal with plays a significant role in photocatalytic recyclability, which intends to premediate that the prepared nanocrystals can be used in industrial persistence. [Display omitted] •Nano ferrites were successfully synthesized by a facile co-precipitate route.•Single phase cubical spinel structure has been observed.•Improvement in magnetic parameters has been observed.•The e- transfer could lead to the observed bleaching of MB under light irradiation.•The catalyst retained its absolute efficiency even after multiple cycles of reuse.