High-efficiency adsorption removal of CR and MG dyes using AlOOH fibers embedded with porous CoFe2O4 nanoparticles

• Published in: Environmental research 2023-01, Vol.216, p.114730, Article 114730
• Main Authors: Cao, Haopeng, Wang, Rongchen, Dou, Kai, Qiu, Junfeng, Peng, Chunyi, Tsidaeva, Natalia, Wang, Wei
• Format: Article
• Language: English
• Subjects: AlOOH; Cobalt ferrites; Dyes; High-efficiency adsorption; pH value
• ISSN: 0013-9351; 1096-0953
• DOI: 10.1016/j.envres.2022.114730

Owing to the toxicity and difficulty in degradation, how to the effective separation for the residual dyes in the aqueous solution is still an issue with great challenge in the area of environmental protection. Now, to high-efficiency removal of organic dyes from the aqueous solution, we design a unique AlOOH/CoFe2O4 adsorbent with porous CoFe2O4 nanoparticles embedded on the AlOOH fibers using a simple hydrothermal technique and calcination process. The structural properties and surface characteristics of the AlOOH/CoFe2O4 composites are detailedly analyzed by XRD, FTIR, XPS, TEM and SEM. Here, the high SBET and specific porous structure are beneficial to improve the adsorption performance of AlOOH/CoFe2O4 adsorbents. Especially, when the molar ratio of AlOOH to CoFe2O4 in the AlOOH/CoFe2O4 fibers is 1:1, an optimal performance on adsorbing anionic Congo red (CR) and cationic methyl green (MG) dyes can be obtained at pH = 6.29, where the corresponding maximum adsorption capacities reach up to 565.0 and 423.7 mg g−1, respectively. Factors leading to the change in the ability of adsorbing CR and MG dyes are systematically discussed, including contact time, temperature, initial concentrations, and pH values of the solutions. Meanwhile, the uptake of CR and MG dyes can best conform to Langmuir isotherm model and pseudo-second-order adsorption kinetics. The thermodynamic analysis verifies that the dye adsorption process is spontaneous and endothermic. Moreover, from the point view of practical application, the good reusability further makes the as-synthesized magnetic AlOOH/CoFe2O4 composite be a perfect adsorbent with efficiently removing both anionic and cationic dyes from aqueous solutions. •A unique AlOOH/CoFe2O4 dye adsorbent was designed.•Maximum adsorption capacities for CR and MG reach 565.0 and 423.7 mg g−1.•Thermodynamic analysis verifies the spontaneous and endothermic adsorption process.•High adsorption capacity originates from electrostatic interaction, ion exchange and hydrogen bonding.