Influence of SEBS-g-MA on morphology, mechanical, and thermal properties of PA6/PP/organoclay nanocomposites

• Published in: European polymer journal 2008-04, Vol.44 (4), p.1023-1039
• Main Authors: Kusmono, Mohd Ishak, Z.A., Chow, W.S., Takeichi, T., Rochmadi
• Format: Article
• Language: English
• Subjects: Applied sciences; Composites; Exact sciences and technology; Forms of application and semi-finished materials; Nanocomposite; Organoclay; Polyamide 6; Polymer industry, paints, wood; Polypropylene; SEBS-g-MA; Technology of polymers
• ISSN: 0014-3057; 1873-1945
• DOI: 10.1016/j.eurpolymj.2008.01.019

Polyamide 6/polypropylene (PA6/PP = 70/30 parts) blends containing 4 phr (parts per hundred resin) of organically modified clay (organoclay) toughened with maleated styrene–ethylene–butylene–styrene (SEBS-g-MA) were prepared by melt compounding using co-rotating twin-screw extruder followed by injection molding. X-ray diffraction (XRD) and transmission electron microscope (TEM) were used to characterize the structure of the nanocomposites. The mechanical properties of the nanocomposites were determined by tensile, flexural, and notched Izod impact tests. The single edge notch three point bending test was used to evaluate the fracture toughness of SEBS-g-MA toughened PA6/PP nanocomposites. Thermal properties were studied by using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). XRD and TEM results indicated the formation of the exfoliated structure for the PA6/PP/organoclay nanocomposites with and without SEBS-g-MA. With the exception of stiffness and strength, the addition of SEBS-g-MA into the PA6/PP/organoclay nanocomposites increased ductility, impact strength and fracture toughness. The elongation at break and fracture toughness of PA6/PP blends and nanocomposites were increased with increasing the testing speed, whereas tensile strength was decreased. The increase in ductility and fracture toughness at high testing speed could be attributed to the thermal blunting mechanism in front of crack tip. DSC results revealed that the presence of SEBS-g-MA had negligible effect on the melting and crystallization behavior of the PA6/PP/organoclay nanocomposites. TGA results showed that the incorporation of SEBS-g-MA increased the thermal stability of the nanocomposite.