Investigation on microscopic forces between methane hydrate particles in gas phase dominated system

• Published in: Fuel (Guildford) 2023-10, Vol.350, p.128776, Article 128776
• Main Authors: Li, Pengfei, Tong, Shikun, Pei, Jihao, Zhang, Jianbo, Guo, Yukun, Liu, Xiao, Fu, Weiqi, Wang, Zhiyuan
• Format: Article
• Language: English
• Subjects: Anti-agglomerant; Methane hydrate; Microscopic force; Steric hindrance effect; Wellbore flow assurance
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2023.128776

•This study systematically measured the CH4 hydrate particle- CH4 hydrate particle cohesive force and CH4 hydrate particle–wall liquid droplet adhesion force under pure water, as well as CH4 hydrate particle–wall liquid droplet adhesion force under anti-agglomerants (AAs).•The mechanism of AAs reducing hydrate adhesion force under low subcooling conditions was investigated.•The mechanism of AAs reducing hydrate adhesion force under high subcooling conditions was investigated.•The steric hindrance effect of AAs molecules at the gas–liquid interface under methane gas phase conditions was discovered, and the effect of AAs on the growth rate of hydrate films was investigated. Hydrate aggregation and deposition on the pipe wall are the main causes of hydrate plugging in pipelines. Microscopic forces between hydrate particles are an important reference for determining the behavior of aggregation or separation from the pipe wall of hydrate particles. Based on a high-pressure visual micro-force measurement system, this study measured the hydrate particle-hydrate particle cohesive force and hydrate particle–wall liquid droplet adhesion force under pure water, as well as hydrate particle–wall liquid droplet adhesion force under anti-agglomerants (AAs). It was found that the magnitude of hydrate particle-hydrate particle cohesive force was ×10 mN/m, and the magnitude of hydrate particle–wall liquid droplet adhesion force was ×103 mN/m. The effects of 4 AAs in the methane gas-dominated system were evaluated from a micro-perspective, revealing that after adding DDBAB, D1021, AEO-9, and CDEA, the maximum reduction of adhesion force was 67%, 64%, 51%, and 53% compared with that under pure water, respectively. The mechanism of AAs reducing adhesion force was further explored, revealing that the adhesion force arose from a liquid bridge and was affected by the gas–water interfacial tension of solutions at low subcoolings. While at high subcoolings, the force was determined by the combined force of the liquid bridge and the hydrate shell. The addition of AAs reduced the gas–water interfacial tension of solutions, and the steric hindrance effect of AA molecules also weakened the tensile strength of the hydrate shell, leading to a decreased adhesion force. These experimental data can help deepen our understanding of the microscopic forces between methane hydrate particles, and provide experimental data and scheme design basis for wellbore flow assurance of deepwater gas wells