Evaluation of Pt/TiO2-Nb2O5 systems in the photocatalytic reforming of glucose for the generation of H2 from industrial effluents

• Published in: Fuel (Guildford) 2024-05, Vol.363, p.130932, Article 130932
• Main Authors: Lara Sandoval, Adriana Elizabeth, Serafin, Jarosław, Murcia Mesa, Julie Joseane, Rojas Sarmiento, Hugo Alfonso, Hernandez Niño, Jhon Sebastian, Llorca, Jordi, Navío Santos, José Antonio, Hidalgo Lõpez, Maria Carmen
• Format: Article
• Language: English
• Subjects: Glucose; Hydrogen; Photocatalysis; Pt-TiO2-Nb2O5; Reforming
• ISSN: 0016-2361
• DOI: 10.1016/j.fuel.2024.130932

[Display omitted] •The photodeposition method was very effective for obtaining the platinized catalysts.•Fluoridation and platinization of commercial oxides made it possible to obtain materials for the production of H2.•Pt-F-Nb2O5 material, showing this as the best material evaluated for the industrial effluents studied.•Catalyst Pt-F-Nb2O5 had the highest H2 production equal to 66 μmol/min/g. Different Pt-TiO2-Nb2O5 systems were synthesized and studied in the photocatalytic reforming of glucose for the generation of H2. The physicochemical properties of the synthesized photocatalysts were analyzed using different characterization techniques from which it was found that fluoridation and sulphation have different effects on the oxides under study such as a protective effect on the crystalline phase in anatase, and greater response in the visible region of the electromagnetic spectrum. The addition of fluorine or sulfates favors the reduction of platinum species on the surface of the semiconductor oxides and a better homogeneity of size and distribution of the particles of this metal. Studies were carried out in the gas phase that allowed the monitoring and quantification of the hydrogen produced from aqueous glucose solutions and it was determined that Pt-F-Nb2O5 and Pt-F-TiO2 are the most efficient materials for the production of hydrogen from this substrate. Similarly, liquid phase studies were carried out with a real sample from a confectionery industry where it was determined that with the material Pt-F-Nb2O5 the highest transformation of glucose is obtained, without the formation of any other sugar or intermediate compound, indicating the preferential production of hydrogen during the photocatalytic reaction. The foregoing demonstrates the potential of the evaluated process in obtaining this gas from the recovery of polluting residues derived from the samples under study.