Hydrogeochemical characteristics of a volcanic-sedimentary aquifer with special emphasis on Fe and Mn content: A case study in Mexico

• Published in: Journal of geochemical exploration 2017-09, Vol.180, p.113-126
• Main Authors: Esteller, M.V., Kondratenko, N., Expósito, J.L., Medina, M., Martin del Campo, M.A.
• Format: Article
• Language: English
• Subjects: Anthropogenic inputs; Fe and Mn; Hydrochemistry; Redox conditions; Volcanic-sedimentary aquifer
• ISSN: 0375-6742; 1879-1689
• DOI: 10.1016/j.gexplo.2017.06.002

Previous studies performed on the volcanic-sedimentary aquifer of the Tenancingo Valley (Mexico) reports high concentrations of Fe, Mn, and NO3−, and water from several wells receives purification treatments due to presence of Fe and Mn. These studies have not achieved conclusive results regarding the origin of Fe and Mn, nor have hydrogeochemical evaluations of the aquifer been performed. The present study aimed to evaluate the physicochemical characteristics of the water and identify the geochemical processes that determine presence of Fe and Mn in groundwater. This characterization was based on physicochemical data from well and spring samples (16 samples) during dry and rainy seasons (June and November 2012, respectively). The EC, temperature and pH ranged from 125 to 793μScm−1, 14.5 to 24.9°C and 6.5 to 8.5pH units, respectively. The Eh values ranged from −219 to 327mV, indicating the existence of both reducing and oxidizing zones. Presence of Fe and Mn was detected in both springs and wells; concentrations were higher in well, exceeding 4mgFeL−1 and 0.5mgMnL−1. Content of Si ranged from 12 to 47mgL−1. A model of the hydrogeochemical behavior of the aquifer was created to highlight the following: i) processes involved in water-rock interactions, including fluctuations in silicate levels that determine anionic and cationic content of water, and ii) redox reactions as the major control processes of Fe and Mn. Water quality for human use is restricted by Fe and Mn content and pH. For irrigation use, significant limitations were not presented. •Physicochemical composition of volcanic-sedimentary aquifer groundwater was studied.•Hydrochemistry data reflect the water-rock interactions (alteration of silicates and ion exchange).•Fe and Mn have been found in springs and wells.•Iron and Mn concentration depends of salinity and redox conditions.•Iron and manganese concentrations of water were higher than the permissible limits in drinking water.