Trinuclear Cu(II) complex with tetrazolyl-pyridine units as a bridging ligand: synthesis, characterization and X-ray structure

• Published in: Inorganica Chimica Acta 2004-01, Vol.357 (2), p.505-512
• Main Authors: Gallardo, Hugo, Meyer, Emerson, Bortoluzzi, Adailton J., Molin, Fernando, Mangrich, Antônio S.
• Format: Article
• Language: English
• Subjects: DNA; Stacking interactions; Tetrazolyl-pyridine; Trinuclear copper complexes
• ISSN: 0020-1693; 1873-3255
• DOI: 10.1016/j.ica.2003.08.012

Reaction of 5-(2-pyridyl)tetrazole with 1,3-dibromopropane afforded three regioisomeric multidentate ligands L 1 , L 2 and L 3 containing two tetradentate pyridyl/tetrazolyl units linked by a flexible propylene spacer. The crystal structures of L 1 and Cu 3(L 1) 2Cl 6 are described. Inter and intramolecular π,π-stacking interactions are observed in the free ligand and in complex 1. Reaction of 5-(2-pyridyl)tetrazole with 1,3-dibromopropane afforded three regioisomeric multidentate ligands L 1 , L 2 and L 3 containing two tetradentate pyridyl/tetrazolyl units linked by a flexible propylene spacer. These compounds were fully characterized by IR, 1H and 13C NMR spectroscopy and elemental analysis. The crystal structure of L 1 was determined. With Cu(II), L 1 formed a trinuclear complex Cu 3(L 1) 2Cl 6. Its structure was determined crystallographically. In the complex, the three copper atoms are found to be in a strict linear arrangement, with the ligand bridging two adjacent copper atoms. The central copper ion is six-co-ordinated. The co-ordination spheres of the terminal copper atoms are distorted square pyramidal. Inter and intramolecular π,π-stacking interactions are observed in the free ligand and in complex 1.